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Influence of Magnetic Field on the Two-Photon Absorption and Hyper-Rayleigh Scattering of Manganese-Zinc Ferrite Nanoparticles

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Autor(es):
Goncalves, Eduardo S. [1] ; Cocca, Leandro H. Z. [2] ; Araujo, Wagner W. R. [1] ; Parekh, Kinnari [3] ; Oliveira, Cristiano L. P. [1] ; Siqueira, Jonathas P. [4] ; Mendonca, Cleber R. [2] ; De Boni, Leonardo [2] ; Neto, Antonio M. Figueiredo [1]
Número total de Autores: 9
Afiliação do(s) autor(es):
[1] Univ Sao Paulo, Inst Fis, BR-05508090 Sao Paulo, SP - Brazil
[2] Univ Sao Paulo, Inst Fis Sao Carlos, Sao Carlos, SP - Brazil
[3] Charotar Univ Sci & Technol, Dr KC Patel R&D Ctr, Changa 388421, Gujarat - India
[4] Univ Estadual Campinas, Inst Fis Gleb Wataghin, BR-13083859 Campinas, SP - Brazil
Número total de Afiliações: 4
Tipo de documento: Artigo Científico
Fonte: Journal of Physical Chemistry C; v. 124, n. 12, p. 6784-6795, MAR 26 2020.
Citações Web of Science: 0
Resumo

Magnetic nanoparticles based on manganese-zinc ferrite presenting spherical and cubic shapes, verified by small-angle X-rays scattering, were studied by means of the hyper-Rayleigh scattering, the Z-Scan technique in the open-aperture configuration, and a spectrally resolved femtosecond transient absorption setup. Hyper-Rayleigh scattering and Z-Scan experiments were performed with applied magnetic field parallel to the laser polarization state and in the perpendicular direction. The hyperpolarizability of spherical nanoparticles was greater than the cubic ones due to the higher volume of spherical nanoparticles and, therefore, the increased influence of the spin-disoriented layer at the surface on cubic nanoparticles, resulting in a smaller orientational average contribution to the hyperpolarizability. The two-photon absorption cross section was the same for both samples, since the basic constituents are the same and the light absorption is not influenced by the surface anisotropy present on magnetic nanoparticles. For both nanoparticles, the measured optical second harmonic and the nonlinear absorption increased during experiments performed in the presence of external field in the parallel configuration, while a decrease was verified for experiments in the perpendicular case, which demonstrates a crystalline anisotropy on the nonlinear optical properties. Transient absorption measurements revealed an ultrafast relaxation process containing at least two separated dynamical processes, the faster with characteristic time below 1 ps and a longer one, much higher than 100 ps. (AU)

Processo FAPESP: 08/57685-7 - Instituto Nacional de Ciência e Tecnologia de Fluídos Complexos
Beneficiário:Antonio Martins Figueiredo Neto
Modalidade de apoio: Auxílio à Pesquisa - Temático
Processo FAPESP: 11/13616-4 - Propriedades ópticas e estruturais de elastômeros e fluidos complexos de interesse biológico
Beneficiário:Antonio Martins Figueiredo Neto
Modalidade de apoio: Auxílio à Pesquisa - Temático
Processo FAPESP: 14/50983-3 - INCT 2014: fluidos complexos
Beneficiário:Antonio Martins Figueiredo Neto
Modalidade de apoio: Auxílio à Pesquisa - Temático
Processo FAPESP: 16/20886-1 - Modernização da linha de Espectroscopia Óptica Não Linear ultrarrápida: Absorção transiente e chave kerr óptica com controle da polarização.
Beneficiário:Leonardo de Boni
Modalidade de apoio: Auxílio à Pesquisa - Regular
Processo FAPESP: 18/11283-7 - Fotônica não linear: espectroscopia e processamento avançado de materiais
Beneficiário:Cleber Renato Mendonça
Modalidade de apoio: Auxílio à Pesquisa - Temático