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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Negishi cross-coupling of organotellurium compounds: synthesis of biaryls, aryl-, and diaryl acetylenes

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Author(s):
Stefani, Helio A. [1] ; Pena, Jesus M. [1] ; Manarin, Flavia [1] ; Ando, Romulo A. [2] ; Leal, Daiana M. [1] ; Petragnani, Nicola [2]
Total Authors: 6
Affiliation:
[1] Univ Sao Paulo, Fac Ciencias Farmaceut, Dept Farm, Sao Paulo - Brazil
[2] Univ Sao Paulo, Inst Quim, Sao Paulo - Brazil
Total Affiliations: 2
Document type: Journal article
Source: Tetrahedron Letters; v. 52, n. 34, p. 4398-4401, AUG 24 2011.
Web of Science Citations: 15
Abstract

A functional group tolerant palladium-catalyzed Negishi coupling of diaryl tellurides with organozinc has been developed. This methodology permits efficient preparation of biaryls, aryl acetylenes and diaryl acetylenes in moderate to good yields. A preliminary study to gain further insight into the reaction was performed using in situ ReactIR technology. (C) 2011 Elsevier Ltd. All rights reserved. (AU)

FAPESP's process: 10/15677-8 - Synthesis of alpha-substituted styrenes
Grantee:Flávia Giovana Manarin
Support Opportunities: Scholarships in Brazil - Post-Doctoral