Enhanced magnetism and suppressed magnetoelastic coupling induced by electron doping in Ca1-x Y x MnReO6

The Ca2MnReO6 double perovskite is a spin-orbit-assisted Mott insulator with exotic magnetic properties, including a largely non-collinear Mn2+ spin arrangement and nearly orthogonal coupling between such spins and the much smaller Re 5d magnetic moments. Here, the electron-doped compound Ca1-x Y x MnReO6 (x = 0.1, 0.2 and 0.3) is reported and a detailed investigation is conducted for x = 0.3. Neutron and x-ray powder diffraction confirm that nearly full chemical order is maintained at the Mn and Re sites under the Y substitution at the Ca site. X-ray absorption measurements and an analysis of the Mn-O/Re-O bond distances show that the Mn oxidation state remains stable at +2 whereas Re is reduced upon doping. The electron doping increases the magnetic ordering temperature from T (c) = 121 to 150 K and also enhances significantly the ferromagnetic component of the Mn spins at the expense of the antiferromagnetic component at the base temperature (T = 3 K). The lattice parameter anomalies at T (c) observed in the parent compound are suppressed by the electron doping. The possible reasons for the enhanced magnetism and the suppressed magnetoelastic coupling in Ca1.7Y0.3MnReO6 are discussed. (AU)