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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Isoniazid-sensing Behavior of a Hybrid Silsesquioxane and Cobalt Pentacyanonitrosylferrate-based Nanocomposite

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de Souza Magossi, Mariana [1] ; de Souza Magossi, Maiara [1] ; Dias Filho, Newton Luiz [1] ; Ribeiro do Carmo, Devaney [1]
Total Authors: 4
[1] Univ Estadual Paulista, Fac Engn Ilha Solteira, Ave Brasil, 56, BR-15385000 Ilha Solteira, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: Electroanalysis; v. 33, n. 8, p. 1886-1894, AUG 2021.
Web of Science Citations: 0

A novel silsesquioxane and cobalt nitroprusside compound was prepared from octa(aminopropyl)silsesquioxane, resulting in a nanocomposite (ACCoN), which was then characterized by different spectroscopic techniques. The cyclic voltammograms of the ACCoN-modified graphite paste electrode indicated a redox pair with a formal potential (E-theta `)=0.38 V, assigned to the (CoFe(II))-Fe-(II)(CN)(5)NO/(CoFe(III))-Fe-(II)(CN)(5)NO redox couple. The ACCoN-modified graphite paste electrode was sensitive to isoniazid concentrations, presenting a linear response at a concentration range from 6.0x10(-7) to 1.0x10(-5) mol L-1, with limit of detection and amperometric sensitivity of 5.53x10(-7) mol L-1 and 0.17 A/mol L-1, respectively. (AU)

FAPESP's process: 18/24576-2 - Hybrid polyhedral oligomeric silsesquioxanes (POSS) and their analytical potentiallity as a sensor for organic and inorganic compounds.
Grantee:Devaney Ribeiro Do Carmo
Support Opportunities: Regular Research Grants