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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Biomimetic Iodofunctionalization of Aromatic and Heteroaromatic Compounds Catalyzed by Selenium Tetrachloride

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Rocha, Beatriz C. O. [1] ; Perecim, Givago P. [1] ; Raminelli, Cristiano [1]
Total Authors: 3
[1] Univ Fed Sao Paulo, Inst Ciencias Ambientais Quim & Farmaceut, Rua Prof Artur Riedel 275, BR-09972270 Diadema, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: SYNOPEN; v. 3, n. 4, p. 142-147, OCT 2019.
Web of Science Citations: 0

A biomimetic iodofunctionalization of aromatic and heteroaromatic compounds has been developed using NaI as a source of iodine and 30% H (2) O (2) as a mild oxidant, as well as SeCl (4) as a commercially available catalyst in water without a co-solvent. The method affords iodinated compounds in isolated yields of 37 to 99%. The catalytic system has potential for the bromination of aromatic substrates. (AU)

FAPESP's process: 17/21990-0 - 2-(Trialkylsilyl)aryl trifluoromethanesulfonates as aryne precursors in the development of methodologies for obtaining nitrogen-containing heterocyclic compounds and total syntheses of bioactive natural products
Grantee:Cristiano Raminelli
Support Opportunities: Regular Research Grants