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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Preparation of Organic Nitrates from Aryldiazoacetates and Fe(NO3)(3)center dot 9H(2)O

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Author(s):
Thurow, Samuel [1] ; Fernandes, Alessandra A. G. [1] ; Quevedo-Acosta, Yovanny [1, 2] ; de Oliveira, Matheus F. [1] ; de Oliveira, Marcelo G. [1] ; Jurberg, Igor D. [1]
Total Authors: 6
Affiliation:
[1] Univ Estadual Campinas, Inst Chem, Rua Monteiro Lobato 270, BR-13083862 Campinas, SP - Brazil
[2] Univ Andes, Dept Chem, Lab Organ Synth Bio & Organocatalysis, Cra 1 18A-12 Q 305, Bogota 111711 - Colombia
Total Affiliations: 2
Document type: Journal article
Source: ORGANIC LETTERS; v. 21, n. 17, p. 6909-6913, SEP 6 2019.
Web of Science Citations: 1
Abstract

A thermal protocol is reported for the formal insertion of nitric acid into aryldiazoacetates using Fe(NO3)(3)center dot 9H(2)O. This strategy is mild and high yielding and allows the preparation of a large variety of members of an unprecedented family of organic nitrates. The nitrate group can be also readily transformed into other functional groups and heterocyclic moieties and can possibly allow new biological explorations of untapped potential associated with their NO-releasing ability. (AU)

FAPESP's process: 17/24017-0 - Application of Isoxazolones in Organic Synthesis
Grantee:Igor Dias Jurberg
Support type: Regular Research Grants
FAPESP's process: 16/02414-5 - Topical and absorbable biomaterials for the local nitric oxide release
Grantee:Marcelo Ganzarolli de Oliveira
Support type: Research Projects - Thematic Grants
FAPESP's process: 18/02520-5 - Nitric oxide-releasing stents comprised of bioabsorbable polinitrosated polyesters
Grantee:Matheus Fernandes de Oliveira
Support type: Scholarships in Brazil - Doctorate (Direct)
FAPESP's process: 17/22164-6 - New transformations involving isoxazol-5-ones
Grantee:Alessandra Aparecida de Godoy Fernandes
Support type: Scholarships in Brazil - Doctorate