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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

In operando evidence of deoxygenation in ionic liquid gating of YBa2Cu3O7-X

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Perez-Munoz, Ana M. ; Schio, Pedro ; Poloni, Roberta ; Fernandez-Martinez, Alejandro ; Rivera-Calzada, Alberto ; Cezar, Julio C. ; Salas-Colera, Eduardo ; Castro, German R. ; Kinney, Joseph ; Leon, Carlos ; Santamaria, Jacobo ; Garcia-Barriocanal, Javier ; Goldman, Allen M.
Total Authors: 13
Document type: Journal article
Source: Proceedings of the National Academy of Sciences of the United States of America; v. 114, n. 2, p. 215-220, JAN 10 2017.
Web of Science Citations: 17

Field-effect experiments on cuprates using ionic liquids have enabled the exploration of their rich phase diagrams {[}Leng X, et al. (2011) Phys Rev Lett 107(2): 027001]. Conventional understanding of the electrostatic doping is in terms of modifications of the charge density to screen the electric field generated at the double layer. However, it has been recently reported that the suppression of the metal to insulator transition induced in VO2 by ionic liquid gating is due to oxygen vacancy formation rather than to electrostatic doping {[}Jeong J, et al. (2013) Science 339(6126): 1402-1405]. These results underscore the debate on the true nature, electrostatic vs. electrochemical, of the doping of cuprates with ionic liquids. Here, we address the doping mechanism of the high-temperature superconductor YBa2Cu3O7-X (YBCO) by simultaneous ionic liquid gating and X-ray absorption experiments. Pronounced spectral changes are observed at the Cu K-edge concomitant with the superconductor-to-insulator transition, evidencing modification of the Cu coordination resulting from the deoxygenation of the CuO chains, as confirmed by first-principles density functional theory (DFT) simulations. Beyond providing evidence of the importance of chemical doping in electric double-layer (EDL) gating experiments with superconducting cuprates, our work shows that interfacing correlated oxides with ionic liquids enables a delicate control of oxygen content, paving the way to novel electrochemical concepts in future oxide electronics. (AU)

FAPESP's process: 13/12537-9 - Electric double layer transistors based on crystalline ionic conductors
Grantee:Pedro Schio de Noronha Muniz
Support Opportunities: Scholarships abroad - Research Internship - Post-doctor