| Full text | |
| Author(s): Show less - |
Ramanitra, Hasina H.
[1]
;
Silva, Hugo Santos
[1, 2]
;
Bregadiolli, Bruna A.
[1, 3]
;
Khoukh, Abdel
[1]
;
Combe, Craig M. S.
[1]
;
Dowland, Simon A.
[4]
;
Begue, Didier
[2]
;
Graeff, Carlos F. O.
[3]
;
Dagron-Lartigau, Christine
[1]
;
Distler, Andreas
[4]
;
Morse, Graham
[5]
;
Hiorns, Roger C.
[6]
Total Authors: 12
|
| Affiliation: | [1] Univ Pau & Pays Adour, IPREM, EPCP, CNRS UMR 5254, 2 Ave President Angot, F-64053 Pau - France
[2] Univ Pau & Pays Adour, IPREM, ECP, CNRS UMR 5254, 2 Ave President Angot, F-64053 Pau - France
[3] UNESP, Dept Fis FC, Av Luiz Edmundo Carrijo Coube 14-01, BR-17033360 Bauru - Brazil
[4] Belectr OPV GmbH, Landgrabenstr 94, D-90443 Nurnberg - Germany
[5] Merck Chem Ltd, Chilworth Tech Ctr, Univ Pkwy, Southampton SO16 7QD, Hants - England
[6] CNRS, IPREM, EPCP, UMR 5254, F-64053 Pau - France
Total Affiliations: 6
|
| Document type: | Journal article |
| Source: | MACROMOLECULES; v. 49, n. 5, p. 1681-1691, MAR 8 2016. |
| Web of Science Citations: | 8 |
| Abstract | |
Fullerene is used as a monomer in this simple method to prepare soluble, well-defined polymers. The sterically controlled azomethine ylide cycloaddition polymerization of fullerene (SACAP) yields macromolecules with molecular weights of around 25 000 g mol(-1). Importantly, cumbersome comonomers are employed to restrict cross linking. Extensive characterizations, with the help of modeling studies, indicate that the polymers are regio-irregular with a majority of trans-3 isomers. Of particular interest is the exceptional ease of preparing polymers with zero metal content. (AU) | |
| FAPESP's process: | 11/02205-3 - Hybrid solar cell based on TiO2 nanoparticles |
| Grantee: | Bruna Andressa Bregadiolli |
| Support Opportunities: | Scholarships in Brazil - Doctorate (Direct) |