graduation at Tecnologia em Processos Químicos from Universidade Tecnológica Federal do Paraná campus Toledo (2011), master's at Chemistry from Universidade Estadual de Campinas (2013) and doctorate at Chemistry from Universidade Estadual de Campinas (2019). (Source: Lattes Curriculum)
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A variety of enantioselective functionalizations of alkenes using palladium oxazoline complexes has been reported in the last few years. The large majority of these processes can have their enantioselectivity rationalized by invoking repulsive steric interactions between the allylic hydrogens of the alkene and a bulky substituent at the oxazoline ligand. However, the origin of the enantio…
Based upon the recent developments in enantioselective Heck-Matsuda arylations, it is proposed herein the use of a substrate oriented methodology in order to achieve not only enantioselectivity but also regioselectivity at cyclic olefins desymmetrization. To carry out this transformation it is proposed uncommon intermediates such as a (valence saturated) pentacoordinated cationic PdII spe…
Considering the expertise of both research groups involved in this project, we propose the development of new enantioselective Heck-Matsuda (EHM) reactions and cascade processes taking advantage of reagents developed by the Hammond's group.In one instance, we plan to use the ionic promoter KCTf3 for the development of a substrate-directed EHM arylation of meso (1R,2S)-cyclohex-4-ene-1,2-d…
| 2 / 2 | Completed scholarships in Brazil |
| 1 / 1 | Completed scholarships abroad |
| 3 / 3 | All Scholarships |
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