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Preparation of Morita-Baylis-Hillman intermediate chiral adducts for synthesis of pyrrolizidine and indolizidine alkaloids

Grant number: 06/00842-8
Support type:Scholarships in Brazil - Scientific Initiation
Effective date (Start): June 01, 2006
Effective date (End): December 31, 2006
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Organic Chemistry
Principal researcher:Fernando Antonio Santos Coelho
Grantee:Tiago de Angelis Cordeiro
Home Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil

Abstract

This undergraduated project has as purpose the preparation of chiral Baylis-Hillman adducts, from chiral aminoaldehydes and use these adducts as substrate for the synthesis of the functionalized skeletons of pyrrolizidinic and indolizidinics alkaloids. Depending on the available time, I intend to synthesize a representative example of an alkaloid of one of the class. (AU)

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