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Synthesis of hierarchical mordenite and chabazite zeolites and their catalytic properties

Grant number: 20/07265-3
Support Opportunities:Scholarships abroad - Research Internship - Post-doctor
Effective date (Start): February 15, 2021
Effective date (End): February 14, 2022
Field of knowledge:Engineering - Chemical Engineering - Chemical Technology
Principal Investigator:Leandro Pierroni Martins
Grantee:Natália Hadler Marins
Supervisor: Yining Huang
Host Institution: Instituto de Química (IQ). Universidade Estadual Paulista (UNESP). Campus de Araraquara. Araraquara , SP, Brazil
Research place: Western University , Canada  
Associated to the scholarship:19/12201-7 - Selected zeolite structures as supports for transition metal oxides for selective conversion of methane into value added chemicals, BP.PD


Utilization of zeolites has been a strategic focus in converting carbon dioxide (CO2) into industrial chemicals because CO2 is one of the main greenhouse gases and has high concentration in atmosphere. Zeolites are microporous crystalline aluminosilicates widely employed in several catalytic reactions due to their selectivity, well-defined microporous structure, high specific area, high thermal stability, and active acidic sites. The feasibility of modifying their physical and chemical properties by changing the synthesis parameters or using post-synthesis treatments may afford them unique features. In this regard, hierarchical zeolites have been prepared for improving the accessibility of active sites by increasing the micropore sizes, introducing mesopores, or reducing crystal sizes. These strategies allow fast diffusion of both reactants and products, improve the catalytic activity, and extend the catalyst lifetime. In this context, this project aims to thoroughly study the crystallization mechanisms of hierarchical SSZ-13 and MOR zeolites in order to achieve the optimized synthesis conditions and high catalytic activity. The hierarchical zeolites will be synthesized, and the effects of crystallization time, temperature, and aging time will be evaluated. In addition, the zeolites will be evaluated regarding the accessibility, activity, and stability of their acid sites. Advanced characterization techniques such as XRD, N2 physisorption, SEM, ICP-AES, in situ solid-state NMR, and NH3-TPD will be used to establish the precise correlations among synthesis-property-function to obtain hierarchical structures for the conversion of methane to methanol and from methanol to products. The outcome of the proposed research will be essential to understanding the crystallization mechanisms of hierarchical zeolites, improving their synthesis conditions, and ultimately boosting their catalytic activity, accessibility of acid sites, and thermal stability. (AU)

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Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
MARINS, NATALIA HADLER; PEREIRA, ELEN MARIA FELICIANO; ALAHAKOON, SANDAMINI H.; HUANG, YINING; MARTINS, LEANDRO. Hierarchical chabazites synthesized by combining primary and secondary structure-directing agents. Microporous and Mesoporous Materials, v. 346, p. 10-pg., . (19/12201-7, 18/01258-5, 20/07265-3, 19/12486-1)

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