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Adsorption and desorption of Cd and Zn in highly fertilized tropical soils

Grant number: 16/22058-9
Support Opportunities:Scholarships abroad - Research Internship - Doctorate
Effective date (Start): August 01, 2017
Effective date (End): July 17, 2018
Field of knowledge:Agronomical Sciences - Agronomy - Soil Science
Principal Investigator:Luís Reynaldo Ferracciú Alleoni
Grantee:Matheus Sampaio Carneiro Barreto
Supervisor: Evert Elzinga
Host Institution: Escola Superior de Agricultura Luiz de Queiroz (ESALQ). Universidade de São Paulo (USP). Piracicaba , SP, Brazil
Research place: Rutgers The State University of New Jersey, Newark, United States  


High rates of lime and fertilizers promote several changes in chemical attributes of highly weathered tropical soils. Some of these changes directly influence the sorption relationship between heavy metals and inorganic and organic soil colloids by affecting the mobility and availability of heavy metals in the soil. The main goal of this research internship abroad, which is linked to the FAPESP research project n° 2016/05870-1, is to evaluate changes in speciation of Cd and Zn in soils solution and their adsorption and desorption mechanisms in highly fertilized soils cropped with oleraceus. Specifically, our objectives are to: i) understand how high bioavailable levels of P, Ca and Mg affect Cd and Zn adsorption in soils and soils compounds ii) identify and characterize soil organic matter compounds that regulate the mobility of Cd and Zn in the soils iii) identify and quantify chemical species of Zn and Cd adsorbed and desorbed in soil colloids and iv) develop a model to describe heavy metals´ adsorption-desorption in soil based in data obtained from isolated soil compounds. Soil sampling and the main routine analytical analyses have already been done. Our expectation is to carry out spectroscopic analysis for soils and soil compounds at the Department of Earth and Environmental Sciences of Rutgers University (Newark, NJ, US). We also plan to obtain and to interpret the data generated by conventional (Fourier transformer infrared, X-ray diffraction, X-ray photon emission) and synchrotron radiation based X-ray absorption techniques. (AU)

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Scientific publications (8)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
BARRETO, MATHEUS SAMPAIO C.; ELZINGA, EVERT J.; ALLEONI, LUIS REYNALDO F.. Hausmannite as potential As(V) filter. Macroscopic and spectroscopic study of As(V) adsorption and desorption by citric acid. Environmental Pollution, v. 262, . (16/05870-1, 16/22058-9)
BARRETO, MATHEUS SAMPAIO C.; SCHELLEKENS, JUDITH; RAMLOGAN, MARLON; ROUFF, ASHAKI A.; ELZINGA, EVERT J.; VIDAL-TORRADO, PABLO; ALLEONI, LUIS REYNALDO F.. Effects of horticulture on soil organic matter properties in highly weathered tropical soils. SOIL & TILLAGE RESEARCH, v. 213, . (16/05870-1, 16/22058-9, 19/26235-0)
BARRETO, MATHEUS SAMPAIO C.; RAMLOGAN, MARLON; OLIVEIRA, DENER MARCIO S.; VERBURG, ERNST EDUARD J.; ELZINGA, EVERT J.; ROUFF, ASHAKI A.; JEMO, MARTIN; ALLEONI, LUIS REYNALDO F.. Thermal stability of soil organic carbon after long-term manure application across land uses and tillage systems in an oxisol. CATENA, v. 200, . (16/05870-1, 16/22058-9)
BARRETO, MATHEUS SAMPAIO CARNEIRO; DOS REIS, JOSIMAR VIERA; MURAOKA, TAKASHI; JEMO, MARTIN; VERGUTZ, LEONARDUS; ALLEONI, LUIS REYNALDO F.. Diffuse reflectance infrared Fourier transform spectroscopy for a qualitative evaluation of plant leaf pigment extraction. ANALYST, v. 146, n. 11, p. 3440-3448, . (14/22262-0, 16/22058-9, 16/05870-1)
GOMES, FREDERICO PRESTES; BARRETO, MATHEUS SAMPAIO C.; AMOOZEGAR, AZIZ; FERRACCIU ALLEONI, LUIS REYNALDO. Immobilization of lead by amendments in a mine-waste impacted soil: Assessing Pb retention with desorption kinetic, sequential extraction and XANES spectroscopy. Science of The Total Environment, v. 807, n. 1, . (16/05870-1, 16/13734-0, 17/11700-4, 16/22058-9)
BARRETO, MATHEUS S. C.; ELZINGA, EVERT J.; ALLEONI, LUIS R. F.. Attenuated total reflectance-Fourier transform infrared study of the effects of citrate on the adsorption of phosphate at the hematite surface. Soil Science Society of America Journal, v. 84, n. 1, p. 57-67, . (16/05870-1, 16/22058-9)
BARRETO, MATHEUS SAMPAIO C.; ELZINGA, EVERT J.; RAMLOGAN, MARLON; ROUFF, ASHAKI A.; ALLEONI, LUIS REYNALDO F.. Calcium enhances adsorption and thermal stability of organic compounds on soil minerals. CHEMICAL GEOLOGY, v. 559, . (16/22058-9, 16/05870-1)
BARRETO, MATHEUS SAMPAIO C.; ELZINGA, EVERT J.; ALLEONI, LUIS REYNALDO F.. The molecular insights into protein adsorption on hematite surface disclosed by in-situ ATR-FTIR/2D-COS study. SCIENTIFIC REPORTS, v. 10, n. 1, . (16/05870-1, 16/22058-9)

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