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Ciclofunctionalizations using Iodine/Iodine (III)

Grant number: 13/00641-6
Support Opportunities:Scholarships in Brazil - Doctorate (Direct)
Effective date (Start): May 01, 2013
Effective date (End): February 28, 2018
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Organic Chemistry
Principal Investigator:Joséf Wilhelm Baader
Grantee:Paulo Scarassati Filho
Host Institution: Instituto de Química (IQ). Universidade de São Paulo (USP). São Paulo , SP, Brazil

Abstract

The synthesis of heterocyclic compounds is of great importance in synthetic organic chemistry and in medicinal chemistry. We are planning to investigate the reactivity of several types of substrates (unsaturated alcohols, amines and carboxylic acids) with the combination of HTIB/I2 aiming the synthesis of O- or N-heterocycles. An important feature of this protocol is that products different from the classic conditions using I2 may be obtained. (AU)

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