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Ionic liquid sorbent phases: synthesis, characterization and applications in GCxGC

Grant number: 12/22375-3
Support Opportunities:Scholarships abroad - Research Internship - Doctorate
Effective date (Start): August 12, 2013
Effective date (End): April 11, 2014
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
Principal Investigator:Fabio Augusto
Grantee:Leandro Wang Hantao
Supervisor: Jared L. Anderson
Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
Research place: University of Toledo (UT), United States  

Abstract

The following proposal for the Research Internship Abroad Fellowship is inserted in the context of the National Institute of Science and Technology (INCT) in Bioanalytics and of the SISBIOTA ("Bioprospecção de fungos sapróbios isolados no PPBIO/semiárido nordestino para o controle de doenças infecciosas em plantas") and FAPESP ("Aplicações de cromatografia gasosa bidimensional abrangente na pesquisa de biomarcadores de resistência a patógenos em vegetais") through the development of novel stationary phases and sorbent materials based on room temperature ionic liquids (RTIL). Here is proposed the molecular design and synthesis of novel materials, which will be explored as stationary phases in the several modalities of Gas Chromatography (Conventional and Multidimensional). Additionally, its applicability as sorbent material in Solid-phase Microextraction devices will also be evaluated. These phases will be evaluated in applications similar to theme of the doctorial thesis of the proponent, in order to enhance the characterization of the metabolic profile of plants and its relation to the resistance of phytopathogens. (AU)

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Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
TOLEDO, BRUNA R.; HANTAO, LEANDRO W.; HO, TIEN D.; AUGUSTO, FABIO; ANDERSON, JARED L.. A chemometric approach toward the detection and quantification of coffee adulteration by solid-phase microextraction using polymeric ionic liquid sorbent coatings. Journal of Chromatography A, v. 1346, p. 1-7, . (12/22375-3)
HANTAO, LEANDRO W.; NAJAFI, ALI; ZHANG, CHENG; AUGUSTO, PABIO; ANDERSON, JARED L.. Tuning the Selectivity of Ionic Liquid Stationary Phases for Enhanced Separation of Nonpolar Analytes in Kerosene Using Multidimensional Gas Chromatography. Analytical Chemistry, v. 86, n. 8, p. 3717-3721, . (12/22375-3)
LEANDRO W. HANTAO; BRUNA R. TOLEDO; FABIO AUGUSTO. FASES ESTACIONÁRIAS DE LÍQUIDOS IÔNICOS EM CROMATOGRAFIA GASOSA: FUNDAMENTOS, AVANÇOS RECENTES E PERSPECTIVAS. Química Nova, v. 39, n. 1, p. 81-93, . (12/22375-3, 11/51896-9)

Please report errors in scientific publications list by writing to: cdi@fapesp.br.