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Electrocatalysis of the hydrogen oxidation reaction and sodium borohydride on dispersed catalysts formed by AB5-type metal hydride alloys

Grant number: 12/09109-2
Support Opportunities:Scholarships in Brazil - Doctorate (Direct)
Effective date (Start): July 01, 2012
Effective date (End): February 29, 2016
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Physical-Chemistry
Principal Investigator:Edson Antonio Ticianelli
Grantee:Waldemir José Paschoalino Junior
Host Institution: Instituto de Química de São Carlos (IQSC). Universidade de São Paulo (USP). São Carlos , SP, Brazil
Associated research grant:09/07629-6 - Electrocatalysis IV: fundamental and applied aspects of electrocatalytic processes, bio-electrocatalysis and kinetic instabilities, AP.BIOEN.TEM
Associated scholarship(s):12/21835-0 - Electrocatalysis of sodium borohydride oxidation reaction on dispersed catalysts formed by AB5-type metal hydride alloys, BE.EP.DD


In this work it will be conducted activities of research and development of electrocatalysts formed Pt and/or Pd nanoparticles supported on a metal hydride alloys, for ultimate use on alkaline fuel cell anodes. The aim is to develop a product presenting hydrogen storage capacity, in the form of hydride, by exposition to gaseous hydrogen or sodium borohydride, and whose anodic process being either the molecular hydrogen oxidation and the absorbed hydride oxidation. (AU)

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Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
PASCHOALINO, WALDEMIR J.; THOMPSON, STEPHEN J.; RUSSELL, ANDREA E.; TICIANELLI, EDSON A.. The Borohydride Oxidation Reaction on La-Ni-Based Hydrogen-Storage Alloys. ChemPhysChem, v. 15, n. 10, SI, p. 2170-2176, . (12/21835-0, 12/09109-2)
Academic Publications
(References retrieved automatically from State of São Paulo Research Institutions)
PASCHOALINO JUNIOR, Waldemir José. Electrocatalysis of the Hydrogen Oxidation Reaction and Sodium Borohydride on Dispersed Catalysts Formed by AB5-type Metal Hydride Alloys. 2016. Doctoral Thesis - Universidade de São Paulo (USP). Instituto de Química de São Carlos (IQSC/BT) São Carlos.

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