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Kinetic resolution of carbonates derived from Morita-Baylis-Hillman adducts and the use of chiral adducts in the synthesis of 1,8-dihydronaphthryridines and dihydroquinolines

Grant number: 12/00548-3
Support Opportunities:Scholarships in Brazil - Scientific Initiation
Effective date (Start): March 01, 2012
Effective date (End): July 31, 2012
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Organic Chemistry
Principal Investigator:Fernando Antonio Santos Coelho
Grantee:Hugo dos Santos
Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil


This undergraduate research project aims at carrying out kinetic resolution of carbonates derived from Morita-Baylis-Hillman, using an enantioselective allylic hydroxylation. The chiral adducts will be employed as starting material for the synthesis of chiral 1,8-dihydronaphthyridines and dihydroquinolines (AU)

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