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Synthesis and use of ormosils as catalysts for water gas-shift reaction

Grant number: 11/05086-5
Support Opportunities:Scholarships in Brazil - Master
Effective date (Start): August 01, 2011
Effective date (End): July 31, 2013
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
Principal Investigator:Ubirajara Pereira Rodrigues Filho
Grantee:Renato Antonio Barba Encarnacion
Host Institution: Instituto de Química de São Carlos (IQSC). Universidade de São Paulo (USP). São Carlos , SP, Brazil

Abstract

The aim of this proposal is to prepare nickel-ormosil based catalysts for the water gás-shift reaction. The impact of the type and amount of functional groups in the ormosil on the nickel dispersion, as well as, the use of phosphotungstate as catalyst activator will be evaluated. The heterogeneous catalysts will be prepared by sol-gel reaction and further nickel and phosphotungstate adsorption. They are going to be characterized by X-Ray Diffraction, Vibrational Spectroscopy, Temperature Programmed Reduction and X-Ray Fluorescence. (AU)

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Academic Publications
(References retrieved automatically from State of São Paulo Research Institutions)
ENCARNACION, Renato Antonio Barba. Sol-gel synthesis of Ni-based catalyst: the effect of phosphotungstic acid and organosilane on the catalytic activity in water-gas shift reaction. 2014. Master's Dissertation - Universidade de São Paulo (USP). Instituto de Química de São Carlos (IQSC/BT) São Carlos.

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