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Synthetic uses of Morita-Baylis-Hillman adducts: new approach to the synthesis of vicinal tricarbonyl compounds

Grant number: 10/04716-2
Support Opportunities:Scholarships in Brazil - Master
Effective date (Start): September 01, 2010
Effective date (End): February 29, 2012
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Organic Chemistry
Principal Investigator:Fernando Antonio Santos Coelho
Grantee:Marília Simão dos Santos
Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil

Abstract

This project has a main subject the development of a new approach to the preparation of vicinal tricarbonyl compounds. These substances can be used as substrate for the syntehsis of biologically active compounds and for the synthesis of heterocyclic compounds, such as heme, which is presented in ceratin enzymes. The proposed method is diret and simple. It uses cheap and easy-to-handle reagents. The methods available in literature to synthesize these compounds are very dificult to reproduce. (AU)

News published in Agência FAPESP Newsletter about the scholarship:
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Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
SANTOS, MARILIA S.; FERNANDES, DANIARA C.; RODRIGUES, JR., MANOEL T.; REGIANI, THAIS; ANDRICOPULO, ADRIANO D.; RUIZ, ANA LUCIA T. G.; VENDRAMINI-COSTA, DEBORA B.; DE CARVALHO, JOAO E.; EBERLIN, MARCOS N.; COELHO, FERNANDO. Diastereoselective Synthesis of Biologically Active Cyclopenta[b]indoles. Journal of Organic Chemistry, v. 81, n. 15, p. 6626-6639, . (13/10449-5, 10/04716-2, 13/07600-3)
Academic Publications
(References retrieved automatically from State of São Paulo Research Institutions)
SANTOS, Marília Simão dos. Exploiting the synthetic potentiality of the Morita-Baylis-Hillman reaction towards the synthesis of vicinal tricarbonyl compounds and cyclopenta[b]indole derivatives. 2012. Master's Dissertation - Universidade Estadual de Campinas (UNICAMP). Instituto de Química Campinas, SP.

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