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Synthetic Applications of the Petasis Reactions of N-acyliminium Ions. Use of enecarbamates in organocatalysis and in the synthesis of sphingosines analogues.

Grant number: 08/00122-0
Support type:Scholarships in Brazil - Doctorate
Effective date (Start): August 01, 2008
Effective date (End): April 30, 2012
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Organic Chemistry
Principal researcher:Carlos Roque Duarte Correia
Grantee:Pablo David Grigol Martinez
Home Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil

Abstract

This proposal intend to prepare nitrogenated heterocycles 2,3-disubstituted with syn stereochemistry through Petasis reaction using N-acyliminium ions generated in situ from lactams. This proposal has either the objective to sinthesize stereoselectively alkaloids with farmacological interest.

News published in Agência FAPESP Newsletter about the scholarship:
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Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
GODOI, MARLA N.; DE AZAMBUJA, FRANCISCO; MARTINEZ, PABLO DAVID G.; MORGON, NELSON H.; SANTOS, VANESSA G.; REGIANI, THAIS; LESAGE, DENIS; DOSSMANN, HELOISE; COLE, RICHARD B.; EBERLIN, MARCOS N.; CORREIA, CARLOS ROQUE D. Revisiting the Intermolecular Fujiwara Hydroarylation of Alkynes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v. 2017, n. 13, p. 1794-1803, APR 3 2017. Web of Science Citations: 9.
Academic Publications
(References retrieved automatically from State of São Paulo Research Institutions)
MARTINEZ, Pablo David Grigol. Endocyclic enecarbamates as substrates in organocatalysis : approaches to sphingoid bases synthesis and bulgecinine analogue. 2013. Doctoral Thesis - Universidade Estadual de Campinas. Instituto de Química.

Please report errors in scientific publications list by writing to: cdi@fapesp.br.