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CINE - Advanced Energy Storage Division

Grant number: 17/11958-1
Support type:Research Grants - Research Centers in Engineering Program
Duration: August 01, 2018 - July 31, 2023
Field of knowledge:Interdisciplinary Subjects
Cooperation agreement: BG E&P Brasil (Shell Group)
Principal researcher:Rubens Maciel Filho
Grantee:Rubens Maciel Filho
Home Institution: Faculdade de Engenharia Química (FEQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
Company: BG E&P Brasil Ltda
Pesquisadores principais:
Antonio Riul Júnior ; Hudson Giovani Zanin
Assoc. researchers:André Luiz Jardini Munhoz ; Gustavo Doubek ; Hudson Giovani Zanin ; Maria Ingrid Rocha Barbosa Schiavon
Associated grant(s):21/14442-1 - EMU approved in grant 2017/11958-1: TGA, AP.EMU
19/04866-9 - EMU approved in grant 2017/11958-1: XPS for surface chemical analysis, AP.EMU
19/04863-0 - EMU approved in grant 2017/11958-1: high ressolution scanning electron microscope FEG-SEM, AP.EMU
Associated scholarship(s):22/02235-4 - Development of solid oxide fuel cells and ethanol reformer, BP.MS
20/14968-0 - Electrodes and electrolytes characterization under dynamic conditions: analysis of evolved gases in different cell assemblies and abuse conditions, BP.MS
20/05626-9 - Control and impact of moisture content in solvents used in electrolytes for Li-O2 batteries, BP.IC
18/16663-2 - Optimized design of porous electrodes for Li-air batteries by controllable functionalized CNT, BP.DR
FAPESP publication:https://media.fapesp.br/bv/uploads/pdfs/fapesp_uk_FukX9vc_166_166.pdf

Abstract

By 2050 it is expected that electricity will move from 18 to 50% of the worldwide energy matrix, renewable sources of energy will expand four times from the current installed capacity, but CO2 emissions are expected to be half of today's value. In this scenario it is imperative to build novel solutions for energy storage that are still unavailable today and can cope with the predicted demands. Also, the worldwide increasing of portable and wearable electronic devices encourages researches on low-cost, flexible, light-weight, and environmentally friendly energy storage and supply devices. In order to effectively store and supply energy, advancement of battery and supercapacitor is vital to make them economically more viable for applications from communications to transport. The ability of those devices to effectively and efficiently store and redistribute energy is highly dependent on the engineering of their constructions and chemistry of the electrode surfaces and electrodes/electrolytes interfaces. High surface area, chemically stable electrodes and electrode/electrolyte interface knowledge are crucial for both batteries and supercapacitors. In order to have insights into the operation and to develop new and more efficient materials and electrolytes for devices a comprehensive chemical and structural understanding of the interface phenomena is fundamental. In this project, we aim to nuclei a Center for Advanced Energy Storage, where we are going to study state-of-the-art batteries and supercapacitors under dynamic conditions by Raman and FTIR spectroscopies and high-intensity synchrotron X-ray. Raman and FTIR will be carried out using optical fibers, coupling cell to spectrometers, allowing us to monitor the reactions during charge and discharge of a device. In situ high resolution and time-resolved X-ray diffraction will be performed in the LNLS line. The in situ techniques will be developed for operando conditions to address fundamental interfacial phenomena that could be linked with multiscale calculations and molecular dynamic simulations. This tailored tool will work in synergy with novel material synthesis based on high surface carbon and fast charge transfer electrodes. The center will also rely on a strong integration from its partners at Brazil and abroad to create a better understanding of the chemistry and engineering for the devices. The Center will properly care about human resource formation, technology transfer, and education and knowledge dissemination under the HUB proposal from LNNano/CNPEM. (AU)

Articles published in Pesquisa FAPESP Magazine about the research grant:
Coches eléctricos impulsados con etanol 
Electric vehicles powered by ethanol 
Articles published in Agência FAPESP Newsletter about the research grant:
Articles published in other media outlets (0 total):
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VEICULO: TITULO (DATA)

Scientific publications (16)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
PIRES, BRUNO MORANDI; NUNES, WILLIAN GONCALVES; FREITAS, BRUNO GUILHERME; OLIVEIRA, FRANCISCA ELENICE RODRIGUES; KATIC, VERA; RODELLA, CRISTIANE BARBIERI; DA SILVA, LEONARDO MORAIS; ZANIN, HUDSON. Characterization of porous cobalt hexacyanoferrate and activated carbon electrodes under dynamic polarization conditions in a sodium-ion pseudocapacitor. JOURNAL OF ENERGY CHEMISTRY, v. 54, p. 53-62, MAR 2021. Web of Science Citations: 0.
VICENTINI, RAFAEL; NUNES, WILLIAN G.; DA COSTA, LENON H.; DA SILVA, LEONARDO M.; FREITAS, BRUNO; PASCON, ALINE M.; VILAS-BOAS, OTAVIO; ZANIN, HUDSON. Multi-walled carbon nanotubes and activated carbon composite material as electrodes for electrochemical capacitors. JOURNAL OF ENERGY STORAGE, v. 33, JAN 2021. Web of Science Citations: 2.
NUNES, WILLIAN G.; FREITAS, BRUNO G. A.; BERALDO, RENATO M.; MACIEL FILHO, RUBENS; DA SILVA, LEONARDO M.; ZANIN, HUDSON. A rational experimental approach to identify correctly the working voltage window of aqueous-based supercapacitors. SCIENTIFIC REPORTS, v. 10, n. 1 NOV 5 2020. Web of Science Citations: 0.
FIATES, JULIANE; ZHANG, YONG; FRANCO, LUIS F. M.; MAGINN, EDWARD J.; DOUBEK, GUSTAVO. Impact of anion shape on Li+ solvation and on transport properties for lithium-air batteries: a molecular dynamics study. Physical Chemistry Chemical Physics, v. 22, n. 28, p. 15842-15852, JUL 28 2020. Web of Science Citations: 0.
CARVALHO, VICTOR S.; MIRANDA, ANDRE N.; NUNES, WILLIAN G.; COSTA, LENON H.; PASCON, ALINE M.; RODELLA, CRISTIANE B.; ZANIN, HUDSON; DOUBEK, GUSTAVO. Radially ordered carbon nanotubes performance for Li-O-2 batteries: Pre- treatment influence on capacity and discharge products. CATALYSIS TODAY, v. 348, n. SI, p. 299-306, MAY 15 2020. Web of Science Citations: 0.
DA SILVA, LEONARDO M.; CESAR, REINALDO; MOREIRA, CASSIO M. R.; SANTOS, JEFERSON H. M.; DE SOUZA, LINDOMAR G.; PIRES, BRUNO MORANDI; VICENTINI, RAFAEL; NUNES, WILLIAN; ZANIN, HUDSON. Reviewing the fundamentals of supercapacitors and the difficulties involving the analysis of the electrochemical findings obtained for porous electrode materials. ENERGY STORAGE MATERIALS, v. 27, p. 555-590, MAY 2020. Web of Science Citations: 0.
NUNES, WILLIAN G.; PIRES, BRUNO M.; DE OLIVEIRA, FRANCISCA E. R.; DE MARQUE, ALINE M. P.; CREMASCO, LETICIA F.; VICENTINI, RAFAEL; DOUBEK, GUSTAVO; DA SILVA, LEONARDO M.; ZANIN, HUDSON. Study of the aging process of nanostructured porous carbon-based electrodes in electrochemical capacitors filled with aqueous or organic electrolytes. JOURNAL OF ENERGY STORAGE, v. 28, APR 2020. Web of Science Citations: 1.
DA SILVA, DEBORA A. C.; PAULISTA NETO, ANTENOR J.; PASCON, ALINE M.; FILETI, EUDES E.; FONSECA, LEONARDO R. C.; ZANIN, HUDSON G. Exploring doped or vacancy-modified graphene-based electrodes for applications in asymmetric supercapacitors. Physical Chemistry Chemical Physics, v. 22, n. 7, p. 3906-3913, FEB 21 2020. Web of Science Citations: 0.
SOARES, DAVI M.; VICENTINI, RAFAEL; PETERLEVITZ, ALFREDO C.; RODELLA, CRISTIANE B.; DA SILVA, LEONARDO M.; ZANIN, HUDSON. Tungsten oxide and carbide composite synthesized by hot filament chemical deposition as electrodes in aqueous-based electrochemical capacitors. JOURNAL OF ENERGY STORAGE, v. 26, DEC 2019. Web of Science Citations: 4.
VICENTINI, RAFAEL; NUNES, WILLIAN; FREITAS, BRUNO G. A.; DA SILVA, LEONARDO M.; SOARES, DAVI MARCELO; CESAR, REINALDO; RODELLA, CRISTIANE B.; ZANIN, HUDSON. Niobium pentoxide nanoparticles @ multi-walled carbon nanotubes and activated carbon composite material as electrodes for electrochemical capacitors. ENERGY STORAGE MATERIALS, v. 22, p. 311-322, NOV 2019. Web of Science Citations: 0.
ZAMBIANCO, NAIARA ALANA; SILVA, TIAGO ALMEIDA; ZANIN, HUDSON; FATIBELLO-FILHO, ORLANDO; JANEGITZ, BRUNO CAMPOS. Novel electrochemical sensor based on nanodiamonds and manioc starch for detection of diquat in environmental samples. DIAMOND AND RELATED MATERIALS, v. 98, OCT 2019. Web of Science Citations: 0.
VICENTINI, RAFAEL; SOARES, DAVI MARCELO; NUNES, WILLIAN; FREITAS, BRUNO; COSTA, LENON; DA SILVA, LEONARDO M.; ZANIN, HUDSON. Core-niobium pentoxide carbon-shell nanoparticles decorating multiwalled carbon nanotubes as electrode for electrochemical capacitors. Journal of Power Sources, v. 434, SEP 15 2019. Web of Science Citations: 0.
VICENTINI, RAFAEL; NUNES, WILLIAN G.; COSTA, LENON H.; DA SILVA, LEONARDO M.; PASCON, ALINE; JACKSON, PALOMA; DOUBEK, GUSTAVO; ZANIN, HUDSON. Highly stable nickel-aluminum alloy current collectors and highly defective multi-walled carbon nanotubes active material for neutral aqueous-based electrochemical capacitors. JOURNAL OF ENERGY STORAGE, v. 23, p. 116-127, JUN 2019. Web of Science Citations: 2.
LI, JINYANG; DOUBEK, GUSTAVO; MCMILLON-BROWN, LYNDSEY; TAYLOR, ANDRE D. Recent Advances in Metallic Glass Nanostructures: Synthesis Strategies and Electrocatalytic Applications. Advanced Materials, v. 31, n. 7 FEB 15 2019. Web of Science Citations: 3.
TELES, JOSE J. S.; FARIA, EMANUEL R.; SANTOS, JEFERSON H. M.; DE SOUSA, LINDOMAR G.; FRANCO, DEBORA V.; NUNES, WILLIAN G.; ZANIN, HUDSON; DA SILVA, LEONARDO M. Supercapacitive properties, anomalous diffusion, and porous behavior of nanostructured mixed metal oxides containing Sn, Ru, and Ir. Electrochimica Acta, v. 295, p. 302-315, FEB 1 2019. Web of Science Citations: 0.
VICENTINI, RAFAEL; COSTA, LENON HENRIQUE; NUNES, WILLIAN; BOAS, OTAVIO VILAS; SOARES, DAVI MARCELO; ALVES, THAYANE ALMEIDA; REAL, CARLA; BUENO, CAROLINE; PETERLEVITZ, ALFREDO CARLOS; ZANIN, HUDSON. Direct growth of mesoporous Carbon on aluminum foil for supercapacitors devices. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 29, n. 12, p. 10573-10582, JUN 2018. Web of Science Citations: 6.

Please report errors in scientific publications list by writing to: cdi@fapesp.br.