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Plasmonic and nonlinear effects in graphene coupled to optical waveguides


This project is currently being submitted within the Thematic Projects line following the advice of FAPESP's Area Coordination, and consists of the same project previously submitted and well refereed in the Young Researchers line [process no. 2012/18400-2]. There has been no change in the budget and only minor amendments in the text were made in this cover page and in section 6 (marked in blue). The team was updated to reflected the personnel that is currently available. Regarding documentation, only the CV, the description of the available infrastructure and equipment, the description of previous funding, as well as forms, were updated. The present proposal aims to study plasmonic and nonlinear optical effects obtained in graphene and other two-dimensional crystals, which will be excited and observed via optical waveguides. Two types of waveguides will be considered: optical fibers and integrated waveguides on planar substrates. Two-dimensional crystals will be incorporated into the waveguide structure in two ways: deposition onto surfaces near the core or introduction into microfluidic channels of the crystals in suspension. In the case of deposition, optical fibers with a D-shaped cross section and waveguides in planar substrates will be used. In the case of crystal suspensions, microstructured optical fibers will be used. For increasing the efficiency of plasmonic effects and of nonlinear optical effects, metallic nanoparticles can be deposited onto graphene. In addition, doping methods, for displacing the Fermi level of graphene, and patterning methods will be studied, aiming at adjusting the plasmonic and optical properties. The resulting waveguides will contribute to a better understanding of the interaction of guided light with the studied nanomaterials, besides presenting a huge technological potential for the development of devices for telecommunications, signal processing and sensing. (AU)

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Scientific publications (34)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
VIANNA, PILAR G.; GRASSESCHI, DANIEL; COSTA, GREICE K. B.; CARVALHO, ISABEL C. S.; DOMINGUES, SERGIO H.; FONTANA, JAKE; DE MATOS, CHRISTIANO J. S.. Graphene Oxide/Gold Nanorod Nanocomposite for Stable Surface-Enhanced Raman Spectroscopy. ACS PHOTONICS, v. 3, n. 6, p. 1027-1035, . (15/11779-4, 15/10405-3, 12/50259-8)
DE OLIVEIRA, RAFAEL E. P.; DE MATOS, CHRISTIANO J. S.. Graphene Based Waveguide Polarizers: In-Depth Physical Analysis and Relevant Parameters. SCIENTIFIC REPORTS, v. 5, . (15/11779-4, 12/50259-8)
STEINBERG, DAVID; DIEGO ZAPATA, JUAN; THOROH DE SOUZA, EUNEZIO A.; SAITO, LUCIA A. M.. Mechanically Exfoliated Graphite Onto D-Shaped Optical Fiber for Femtosecond Mode-Locked Erbium-Doped Fiber Laser. Journal of Lightwave Technology, v. 36, n. 10, p. 1868-1874, . (16/25836-2, 15/11779-4, 12/50259-8)
ETCHEVERRY, SEBASTIAN; ARAUJO, LEONARDO F.; DA COSTA, GREICE K. B.; PEREIRA, JOAO M. B.; CAMARA, ALEXANDRE R.; NACIRI, JAWAD; RATNA, BANAHALLI R.; HERNANDEZ-ROMANO, IVAN; DE MATOS, CHRISTIANO J. S.; CARVALHO, ISABEL C. S.; et al. Microsecond switching of plasmonic nanorods in an all-fiber optofluidic component. OPTICA, v. 4, n. 8, p. 864-870, . (12/05916-0, 15/11779-4)
GEROSA, RODRIGO M.; SUAREZ, FELIPE G.; VIANNA, PILAR G.; DOMINGUES, SERGIO H.; DE MATOS, CHRISTIANO J. S.. One-step deposition and in-situ reduction of graphene oxide in photonic crystal fiber for all-fiber laser mode locking. OPTICS AND LASER TECHNOLOGY, v. 121, . (15/11779-4, 12/50259-8)
BARCELOS, INGRID D.; BECHTEL, HANS A.; DE MATOS, CHRISTIANO J. S.; BAHAMON, DARIO A.; KAESTNER, BERND; MAIA, FRANCISCO C. B.; FREITAS, RAUL O.. Probing Polaritons in 2D Materials with Synchrotron Infrared Nanospectroscopy. ADVANCED OPTICAL MATERIALS, v. 8, n. 5, SI, . (15/11779-4, 12/50259-8, 18/07276-5)
GIL-MOLINA, A.; CASTANEDA, J. A.; LONDONO-GIRALDO, D. F.; GABRIELLI, L. H.; CARDENAS, A. M.; FRAGNITO, H. L.. High-order dispersion mapping of an optical fiber. Optics Express, v. 28, n. 3, p. 4258-4273, . (12/50259-8, 15/11779-4, 19/16793-6, 17/16151-9, 18/08988-9)
GRASSESCHI, D.; BAHAMON, D. A.; MAIA, F. C. B.; BARCELOS, I. D.; FREITAS, R. O.; DE MATOS, C. J. S.. an der Waals materials as dielectric layers for tailoring the near-field photonic response of surface. Optics Express, v. 30, n. 1, p. 255-264, . (12/50259-8, 18/25339-4, 19/14017-9, 15/10405-3, 15/11779-4)
DA SILVA-NETO, MANOEL L.; BARBOSA-SILVA, RENATO; DE ARAUJO, CID B.; DE MATOS, CHRISTIANO J. S.; JAWAID, ALI M.; RITTER, ALLYSON J.; VAIA, RICHARD A.; GOMES, ANDERSON S. L.. Hyper-Rayleigh scattering in 2D redox exfoliated semi-metallic ZrTe2 transition metal dichalcogenide. Physical Chemistry Chemical Physics, v. 22, n. 47, p. 27845-27849, . (18/25339-4, 15/11779-4)
MALDONADO, MELISSA; DA SILVA NETO, MANOEL L.; VIANNA, PILAR G.; RIBEIRO, HENRIQUE B.; DE ARAUJO, CID B.; DE MATOS, CHRISTIANO J. S.; SEIXAS, LEANDRO; JAWAID, ALI M.; BUSCH, ROBERT; RITTER, ALLYSON J.; et al. Femtosecond nonlinear refraction of 2D semi-metallic redox exfoliated ZrTe2 at 800nm. Applied Physics Letters, v. 118, n. 1, . (18/25339-4, 17/20100-0, 18/04926-9, 15/11779-4)
GARCIA-BASABE, YUNIER; GORDO, VANESSA ORSI; DAMINELLI, LARA M.; MENDOZA, CESAR D.; VICENTIN, FLAVIO C.; MATUSALEM, FILIPE; ROCHA, ALEXANDRE R.; DE MATOS, CHRISTIANO J. S.; LARRUDE, DUNIESKYS G.. Interfacial electronic coupling and band alignment of P3HT and exfoliated black phosphorous van der Waals heterojunctions. Applied Surface Science, v. 541, . (18/08988-9, 15/11779-4, 17/02317-2)
VIANNA, PILAR G.; ALMEIDA, ALINE DOS S.; GEROSA, RODRIGO M.; BAHAMON, DARIO A.; DE MATOS, CHRISTIANO J. S.. Second-harmonic generation enhancement in monolayer transition-metal dichalcogenides by using an epsilon-near-zero substrate. NANOSCALE ADVANCES, v. 3, n. 1, p. 272-278, . (15/11779-4, 18/25339-4)
STEINBERG, DAVID; ZAPATA, JUAN DIEGO; SAITO, LUCIA A. M.; DE SOUZA, EUNEZIO A. THOROH. Study of Pulse Formation in an EDFL Under a Large Dispersion Variation Hybridly Mode-Locked by Graphene and Nonlinear Polarization Rotation. IEEE Photonics Journal, v. 13, n. 2, . (15/11779-4, 16/25836-2, 12/50259-8)
RIBEIRO, HENRIQUE B.; PIMENTA, MARCOS A.; DE MATOS, CHRISTIANO J. S.. Raman spectroscopy in black phosphorus. Journal of Raman Spectroscopy, v. 49, n. 1, SI, p. 76-90, . (15/11779-4, 12/50259-8)
KESSLER, FELIPE; MUNOZ, PABLO A. R.; PHELAN, CIARAN; ROMANI, ERIC C.; LARRUDE, DUNIESKYS R. G.; FREIRE JUNIOR, FERNANDO L.; DE SOUZA, EUNEZIO A. THOROH; DE MATOS, CHRISTIANO J. S.; FECHINE, GUILHERMINO J. M.. Direct dry transfer of CVD graphene to an optical substrate by in situ photo-polymerization. Applied Surface Science, v. 440, p. 55-60, . (15/12734-4, 14/22840-3, 12/50259-8, 15/11779-4)
GIL-MOLINA, A.; PEREZ-RAMIREZ, A.; RAMIREZ, J. C.; GABRIELLI, L. H.; FRAGNITO, H. L.. Shift of zero-dispersion wavelength in bent optical fibers. Optics Express, v. 26, n. 6, p. 6700-6714, . (15/11779-4, 08/57857-2, 12/50259-8, 13/20180-3)
TORRES, V; SILVA, P.; DE SOUZA, E. A. T.; SILVA, L. A.; BAHAMON, D. A.. Valley notch filter in a graphene strain superlattice: Green's function and machine learning approach. Physical Review B, v. 100, n. 20, . (15/11779-4, 12/50259-8, 18/07276-5)
VIANNA, PILAR G.; GRASSESCHI, DANIEL; DOMINGUES, SERGIO H.; DE MATOS, CHRISTIANO J. S.. Real-time optofluidic surface-enhanced Raman spectroscopy based on a graphene oxide/gold nanorod nanocomposite. Optics Express, v. 26, n. 18, p. 22698-22708, . (15/11779-4, 15/10405-3, 12/50259-8)
GEROSA, RODRIGO M.; STEINBERG, DAVID; NAGAOKA, DANILO A.; ZAPATA, JUAN D.; DOMINGUES, SERGIO H.; THOROH DE SOUZA, EUNEZIO A.; SAITO, LUCIA A. M.. Liquid phase exfoliated black phosphorus and reduced graphene oxide polymer-based saturable absorbers fabrication using the droplet method for mode-locking applications. OPTICS AND LASER TECHNOLOGY, v. 106, p. 107-112, . (16/25836-2, 15/11779-4, 12/50259-8)
GRASSESCHI, D.; BAHAMON, D. A.; MAIA, F. C. B.; CASTRO NETO, A. H.; FREITAS, R. O.; DE MATOS, C. J. S.. Oxygen impact on the electronic and vibrational properties of black phosphorus probed by synchrotron infrared nanospectroscopy. 2D MATERIALS, v. 4, n. 3, . (15/11779-4, 15/10405-3, 12/50259-8)
STEINBERG, DAVID; GEROSA, RODRIGO M.; PELLICER, FERNANDA N.; ZAPATA, JUAN D.; DOMINGUES, SERGIO H.; THOROH DE SOUZA, EUNEZIO A.; SAITO, LUCIA A. M.. Graphene oxide and reduced graphene oxide as saturable absorbers onto D-shaped fibers for sub 200-fs EDFL mode-locking. OPTICAL MATERIALS EXPRESS, v. 8, n. 1, p. 144-156, . (16/25836-2, 15/11779-4, 12/50259-8)
WOODWARD, R. I.; MURRAY, R. T.; PHELAN, C. F.; DE OLIVEIRA, R. E. P.; RUNCORN, T. H.; KELLEHER, E. J. R.; LI, S.; DE OLIVEIRA, E. C.; FECHINE, G. J. M.; EDA, G.; et al. Characterization of the second- and third-order nonlinear optical susceptibilities of monolayer MoS2 using multiphoton microscopy. 2D MATERIALS, v. 4, n. 1, . (15/11779-4, 14/50460-0, 15/12734-4, 12/50259-8)
ALDAYA, I.; GIL-MOLINA, A.; PITA, J. L.; GABRIELLI, L. H.; FRAGNITO, H. L.; DAINESE, P.. Nonlinear carrier dynamics in silicon nano-waveguides. OPTICA, v. 4, n. 10, p. 1219-1227, . (15/11779-4, 12/50259-8, 15/04113-0, 13/20180-3)
BATISTA, ANDRE JAQUES; VIANNA, PILAR GREGORY; RIBEIRO, HENRIQUE BUCKER; SANTIAGO DE MATOS, CHRISTIANO JOSE; LEONIDAS GOMES, ANDERSON STEVENS. QR code micro-certified gemstones: femtosecond writing and Raman characterization in Diamond, Ruby and Sapphire. SCIENTIFIC REPORTS, v. 9, . (15/11779-4, 17/20100-0, 12/50259-8)
RODRIGUES, MANUEL J. L. F.; DE MATOS, CHRISTIANO J. S.; HO, YI WEI; PEIXOTO, HELDER; DE OLIVEIRA, RAFAEL E. P.; WU, HSIN-YU; CASTRO NETO, ANTONIO H.; VIANA-GOMES, JOSE. Resonantly Increased Optical Frequency Conversion in Atomically Thin Black Phosphorus. Advanced Materials, v. 28, n. 48, p. 10693+, . (15/11779-4, 12/50259-8)
FERES, FLAVIO H.; BARCELOS, INGRID D.; MAYER, RAFAEL A.; DOS SANTOS, THIAGO M.; FREITAS, RAUL O.; RASCHKE, MARKUS B.; BAHAMON, DARIO A.; MAIA, FRANCISCO C. B.. Dipole modelling for a robust description of subdiffractional polariton waves. NANOSCALE, v. 11, n. 44, p. 21218-21226, . (18/05425-3, 15/11779-4, 19/08818-9, 18/07276-5)
AIUB, EDUARDO J.; STEINBERG, DAVID; THOROH DE SOUZA, EUNEZIO A.; SAITO, LUCIA A. M.. 200-fs mode-locked Erbium-doped fiber laser by using mechanically exfoliated MoS2 saturable absorber onto D-shaped optical fiber. Optics Express, v. 25, n. 9, p. 10546-10552, . (15/11779-4, 14/50460-0, 12/50259-8)
RIBEIRO, H. B.; VILLEGAS, C. E. P.; BAHAMON, D. A.; MURACA, D.; CASTRO NETO, A. H.; DE SOUZA, E. A. T.; ROCHA, A. R.; PIMENTA, M. A.; DE MATOS, C. J. S.. Edge phonons in black phosphorus. NATURE COMMUNICATIONS, v. 7, . (12/24227-1, 11/01235-6, 12/50259-8, 15/11779-4, 11/11973-4)
ZAPATA, J. D.; STEINBERG, D.; SAITO, L. A. M.; DE OLIVEIRA, R. E. P.; CARDENAS, A. M.; THOROH DE SOUZA, E. A.. Efficient graphene saturable absorbers on D-shaped optical fiber for ultrashort pulse generation. SCIENTIFIC REPORTS, v. 6, . (15/11779-4, 12/50259-8, 15/12716-6)
LIU, HE; GRASSESCHI, DANIEL; DODDA, AKHIL; FUJISAWA, KAZUNORI; OLSON, DAVID; KAHN, ETHAN; ZHANG, FU; ZHANG, TIANYI; LEI, YU; BRANCO, RICARDO BRAGA NOGUEIRA; et al. Spontaneous chemical functionalization via coordination of Au single atoms on monolayer MoS2. SCIENCE ADVANCES, v. 6, n. 49, . (12/50259-8, 15/11779-4, 17/01817-1)
MALDONADO, MELISSA E.; DAS, AVISHEK; JAWAID, ALI M.; RITTER, ALLYSON J.; VAIA, RICHARD A.; NAGAOKA, DANILO A.; VIANNA, PILAR G.; SEIXAS, LEANDRO; DE MATOS, CHRISTIANO J. S.; BAEV, ALEXANDER; et al. Nonlinear Optical Interactions and Relaxation in 2D Layered Transition Metal Dichalcogenides Probed by Optical and Photoacoustic Z-Scan Methods. ACS PHOTONICS, v. 7, n. 12, p. 5440-5447, . (18/25339-4, 15/11779-4)
BAHAMON, DARIO A.; GOMEZ-SANTOS, G.; STAUBER, T.. Emergent magnetic texture in driven twisted bilayer graphene. NANOSCALE, v. 12, n. 28, p. 15383-15392, . (15/11779-4, 18/07276-5)
MALDONADO, MELISSA; DA SILVA NETO, MANOEL L.; VIANNA, PILAR G.; RIBEIRO, HENRIQUE B.; GORDO, VANESSA O.; CARVALHO, ISABEL C. S.; MENEZES, LEONARDO DE S.; DE ARAUJO, CID B.; DE MATOS, CHRISTIANO J. S.; SEIXAS, LEANDRO; et al. Femtosecond Nonlinear Optical Properties of 2D Metallic NbS2 in the Near Infrared. Journal of Physical Chemistry C, v. 124, n. 28, p. 15425-15433, . (17/20100-0, 12/50259-8, 15/11779-4, 18/04926-9)
RIBEIRO, H. B.; RAMOS, S. L. L. M.; SEIXAS, L.; DE MATOS, C. J. S.; PIMENTA, M. A.. Edge phonons in layered orthorhombic GeS and GeSe monochalcogenides. Physical Review B, v. 100, n. 9, . (15/11779-4, 12/50259-8, 17/20100-0, 18/04926-9)

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