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Vibrational spectroscopy in condensed phases

Grant number: 12/13119-3
Support Opportunities:Research Projects - Thematic Grants
Duration: April 01, 2013 - March 31, 2018
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Physical-Chemistry
Principal Investigator:Mauro Carlos Costa Ribeiro
Grantee:Mauro Carlos Costa Ribeiro
Host Institution: Instituto de Química (IQ). Universidade de São Paulo (USP). São Paulo , SP, Brazil
Pesquisadores principais:
Dalva Lucia Araujo de Faria ; Marcia Laudelina Arruda Temperini ; Paola Corio ; Paulo Sergio Santos
Associated researchers:Rômulo Augusto Ando
Associated grant(s):15/11149-0 - High-pressure Raman Spectroscopy: monitoring the behavior and reactivity of liquids and conducting polymers, AV.EXT
14/25528-0 - Chemical contributions to astrobiology, AV.EXT
13/24235-7 - Properties of Surface Enhanced Raman Spectroscopy (SERS) at unique condition, AV.EXT
Associated scholarship(s):15/24818-8 - Excited state dynamics of donor ­acceptor systems investigated by time resolved spectroscopic techniques, BE.PQ
16/06495-0 - Raman Spectroscopy in Archeochemistry: investigation on the Mochica culture traces from Sipan. I. Investigation on carotenoids in shells of archaeological interest, BP.IC
15/25807-0 - Investigating the catalytic activity of plasmonic nanostructures by SERS, BP.PD
 + associated scholarships 16/01180-0 - Manufacture of high performance SERS substrates using gold nanoparticles immobilized on polyaniline nanofibers, BP.IC
15/05803-0 - Ionic liquid structure under high pressure, BP.PD
15/07516-8 - Collective dynamics of ionic liquids, BP.DD
14/15107-8 - High pressure Raman spectroscopy, from aromatics amines to conducting polymers., BP.PD
14/15049-8 - A Raman spectroscopy study of the glass transition of ionic liquids under high pressure., BP.PD
14/13134-8 - A study by computational simulation of ionic liquids stress heterogeneity, BP.PD
14/07841-3 - Intensity and spectral fluctuations study in a single-molecule SERS spectra, BP.PD
13/23234-7 - Ionic Liquids for CO2 Capture: Physical vs. Chemical Absorption., BP.DR
13/19949-0 - Hybrid systems between titanium dioxide and carbon nanotubes in photocatalytic processes, BP.IC
13/07741-6 - Vibrational Spectroscopy and Thermodynamic Properties of Ionic Liquids under High Pressure, BP.DR - associated scholarships

Abstract

Several research activities in the Laboratório de Espectroscopia Molecular, Instituto de Química, Universidade de São Paulo, LEM/IQ-USP, are related with infrared and Raman spectroscopy of condensed phases, such as interfaces, colloids, electrodes, molecular and ionic liquids, molecular probes in non-aqueous solvents, polymers, carbon nanotubes etc. In this research project, spectroscopic properties (e.g. signal enhancement) and physicochemical properties (conductivity, structural heterogeneity, solvation etc.) resulting from intermolecular interactions in condensed phases will be considered in different studies. The parameters responsible for signal enhancement in surface-enhanced Raman scattering (SERS) will be investigated as they are related to interactions between the molecule and the SERS active sites. In case of very low concentrations, the analysis of intensity fluctuations at different sites of the surface will be based on frequency shifts, and also on relative intensity and bandwidth, since such fluctuations are due to interactions between the molecule and the surface and solvent. This work aims the development of surfaces of controlled size and shape exhibiting high enhancement ability, the study of photochemical reactions taking place on nanoparticles and morphology of polymers, and development of selective sensors. The research activities related to structure and dynamics of liquids include molecular and ionic liquids, supercritical and supercooled liquids, and solute - solvent interactions including gases solvation in ionic liquids. Frequency shift and Raman bandshape, which are due to vibrational and reorientational relaxation processes in the liquid phase, will be investigated as a function of temperature and pressure. The analysis of vibrational spectra of liquids will be complemented by molecular dynamics computer simulations. (AU)

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Scientific publications (47)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
BALLOTTIN, DANIELA; FULAZ, STEPHANIE; SOUZA, MICHELE L.; CORIO, PAOLA; RODRIGUES, ALEXANDRE G.; SOUZA, ANA O.; GASPARI, PRISCYLA M.; GOMES, ALEXANDRE F.; GOZZO, FABIO; TASIC, LJUBICA. Elucidating Protein Involvement in the Stabilization of the Biogenic Silver Nanoparticles. NANOSCALE RESEARCH LETTERS, v. 11, . (12/13119-3, 11/00222-8)
LIMA, THAMIRES A.; PASCHOAL, VITOR H.; FARIA, LUIZ F. O.; RIBEIRO, MAURO C. C.. Unraveling the Stepwise Melting of an Ionic Liquid. Journal of Physical Chemistry B, v. 121, n. 17, p. 4650-4655, . (15/05803-0, 15/07516-8, 12/13119-3, 14/15049-8)
FARIA, LUIZ F. O.; PASCHOAL, VITOR H.; LIMA, THAMIRES A.; FERREIRA, FABIO F.; FREITAS, RAFAEL S.; RIBEIRO, MAURO C. C.. Local Order Disorder Transition Driving by Structural Heterogeneity in a Benzyl Functionalized Ionic Liquid. Journal of Physical Chemistry B, v. 121, n. 42, p. 9902-9909, . (15/05803-0, 12/13119-3, 14/15049-8)
GARCIA, MARCO A. S.; IBRAHIM, MAHMOUD; COSTA, JEAN C. S.; CORIO, PAOLA; GUSEVSKAYA, ELENA V.; DOS SANTOS, EDUARDO N.; PHILIPPOT, KARINE; ROSSI, LIANE M.. Study of the influence of PPh3 used as capping ligand or as reaction modifier for hydroformylation reaction involving Rh NPs as precatalyst. APPLIED CATALYSIS A-GENERAL, v. 548, n. SI, p. 136-142, . (12/13119-3, 14/15159-8)
PUGLIERI, THIAGO S.; LAVEZZO, ARIANE S.; DOS SANTOS, ISABELA F. S.; DE FARIA, DALVA L. A.. Investigation on the hazing of a Brazilian contemporary painting. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, v. 159, p. 117-122, . (12/13119-3, 11/13760-8)
FARIA, LUIZ F. O.; NOBREGA, MARCELO M.; TEMPERINI, MARCIA L. A.; BINI, ROBERTO; RIBEIRO, MAURO C. C.. Triggering the Chemical Instability of an Ionic Liquid under High Pressure. Journal of Physical Chemistry B, v. 120, n. 34, p. 9097-9102, . (15/05803-0, 14/15107-8, 15/09763-2, 12/13119-3)
FAZIO, ALEJANDRA T.; CAVICCHIOLI, ANDREA; PENNA, DAYSI S. A.; CHAMBERGO, FELIPE S.; DE FARIA, DALVA L. A.. Towards a better comprehension of biodeterioration in earthen architecture: Study of fungi colonisation on historic wall surfaces in Brazil. JOURNAL OF CULTURAL HERITAGE, v. 16, n. 6, p. 934-938, . (12/13119-3, 12/05356-5)
NOBREGA, MARCELO M.; TEMPERINI, MARCIA L. A.; BINI, ROBERTO. Probing the Chemical Stability of Aniline under High Pressure. Journal of Physical Chemistry C, v. 121, n. 13, p. 7495-7501, . (12/13119-3, 15/09763-2, 14/15107-8)
PUGLIERI, THIAGO S.; DE FARIA, DALVA L. A.; CAVICCHIOLI, ANDREA. Indoor corrosion of Pb: Effect of formaldehyde concentration and relative humidity investigated by Raman microscopy. VIBRATIONAL SPECTROSCOPY, v. 71, p. 24-29, . (12/13119-3, 11/13760-8)
BERNARDINO, N. D.; BROWN-XU, S.; GUSTAFSON, T. L.; DE FARIA, D. L. A.. Time-Resolved Spectroscopy of Indigo and of a Maya Blue Simulant. Journal of Physical Chemistry C, v. 120, n. 38, p. 21905-21914, . (12/05643-4, 12/13119-3, 13/25900-4)
HOHER, KARINA; CARDOSO, PIERCARLO F.; LEPRE, LUIZ F.; ANDO, ROMULO A.; SIQUEIRA, LEONARDO J. A.. Molecular dynamics and a spectroscopic study of sulfur dioxide absorption by an ionic liquid and its mixtures with PEO. Physical Chemistry Chemical Physics, v. 18, n. 41, p. 28901-28910, . (13/23234-7, 12/13119-3, 11/22263-8)
BERNARDINO, NATHALIA D'ELBOUX; IZUMI, CELLY M. S.; DE FARIA, DALVA L. A.. Fake turquoises investigated by Raman microscopy. Forensic Science International, v. 262, p. 196-200, . (12/05643-4, 12/13119-3)
LIMA, THAMIRES A.; LI, ZHIXIA; TYAGI, MADHUSUDAN; RIBEIRO, MAURO C. C.; Z, Y.. Spatial and thermal signatures of alpha and beta relaxations in glassy and glacial aliphatic ionic liquids. Journal of Chemical Physics, v. 150, n. 14, . (16/24241-5, 12/13119-3)
LEPRE, L. F.; PISON, L.; SIQUEIRA, L. J. A.; ANDO, R. A.; GOMES, M. F. COSTA. Improvement of carbon dioxide absorption by mixing poly(ethylene glycol) dimethyl ether with ammonium-based ionic liquids. Separation and Purification Technology, v. 196, n. SI, p. 10-19, . (13/23234-7, 12/13119-3, 15/07145-0, 11/22263-8)
MONEZI, NATALIA M.; ANDO, ROMULO A.. Spectroscopic Characterization of Charge Transfer Complexes of TCNE with Aromatic Amines - The First Step of Tricyanovinylation Reaction. Journal of the Brazilian Chemical Society, v. 28, n. 9, p. 1665-1672, . (12/13119-3)
THIAGO S. PUGLIERI; RAUL DE O. FREITAS; FRANCISCO C. B. MAIA; DALVA L. A. DE FARIA. NANOESPECTROSCOPIA DE ABSORÇÃO DE RADIAÇÃO SÍNCROTRON NO INFRAVERMELHO PARA NANOESPECIAÇÃO DE PRODUTOS DE CORROSÃO METÁLICA. Química Nova, v. 42, n. 9, p. 1050-1055, . (16/21070-5, 11/13760-8, 12/13119-3)
FANETTI, SAMUELE; NOBREGA, MARCELO M.; DZIUBEK, KAMIL; CITRONI, MARGHERITA; SELLA, ANDREA; MCMILLAN, PAUL F.; HANFLAND, MICHAEL; BINI, ROBERTO. Structure and reactivity of 2,4,6-tricyano-1,3,5-triazine under high-pressure conditions. CrystEngComm, v. 21, n. 30, p. 4493-4500, . (12/13119-3, 14/15107-8, 15/09763-2)
PENNA, TATIANA C.; PASCHOAL, VITOR H.; FARIA, LUIZ F. O.; RIBEIRO, MAURO C. C.. Estimating density of ionic liquids under very high pressure. JOURNAL OF MOLECULAR LIQUIDS, v. 265, p. 510-516, . (15/05803-0, 15/07516-8, 12/13119-3, 13/07741-6)
LIMA, THAMIRES A.; FARIA, LUIZ F. O.; PASCHOAL, VITOR H.; RIBEIRO, MAURO C. C.. Communication: Glass transition and melting lines of an ionic liquid. Journal of Chemical Physics, v. 148, n. 17, . (15/05803-0, 15/07516-8, 12/13119-3, 14/15049-8)
BERNARDINO, N. D.; DE FARIA, D. L. A.; NEGRON, V, A. C.. Applications of Raman spectroscopy in archaeometry: An investigation of pre-Columbian Peruvian textiles. JOURNAL OF ARCHAEOLOGICAL SCIENCE-REPORTS, v. 4, p. 23-31, . (12/05643-4, 12/13119-3)
FARIA, LUIZ F. O.; NOBREGA, MARCELO M.; FALSINI, NAOMI; FANETTI, SAMUELE; TEMPERINI, MARCIA L. A.; BINI, ROBERTO; RIBEIRO, MAURO C. C.. Structure and Reactivity of the Ionic Liquid 1-Allyl-3-methylimidazolium Iodide under High Pressure. Journal of Physical Chemistry B, v. 123, n. 8, p. 1822-1830, . (16/21070-5, 15/09763-2, 12/13119-3, 15/05803-0, 14/15107-8)
PENNA, TATIANA C.; RIBEIRO, MAURO C. C.. Vibrational frequency shift of 1-alkyl-3-methylimidazolium tetrafluoroborate ionic liquids under high pressure. JOURNAL OF MOLECULAR LIQUIDS, v. 278, p. 213-218, . (12/13119-3, 13/07741-6, 16/21070-5)
NOBREGA, MARCELO M.; TEIXEIRA-NETO, ERICO; CAIRNS, ANDREW B.; TEMPERINI, MARCIA L. A.; BINI, ROBERTO. One-dimensional diamondoid polyaniline-like nanothreads from compressed crystal aniline. CHEMICAL SCIENCE, v. 9, n. 1, p. 254-260, . (12/13119-3, 14/15107-8, 15/09763-2)
MAMIAN-LOPEZ, MONICA BENICIA; MIGUEL, RODRIGO BERNARDI; ARAKI, KOITI; TEMPERINI, MARCIA L. A.; DA COSTA FERREIRA, ANA MARIA. Multivariate probing of antitumor metal-based complexes damage on living cells through Raman imaging. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, v. 244, . (14/07841-3, 16/21070-5, 12/13119-3, 18/21489-1, 13/07937-8)
FANETTI, SAMUELE; CITRONI, MARGHERITA; DZIUBEK, KAMIL; NOBREGA, MARCELO MEDRE; BINI, ROBERTO. The role of H-bond in the high-pressure chemistry of model molecules. JOURNAL OF PHYSICS-CONDENSED MATTER, v. 30, n. 9, . (12/13119-3, 14/15107-8, 15/09763-2)
ABREU, DIERIC S.; TEMPERINI, MARCIA L. A.; ABRUNA, HECTOR D.; DIOGENES, IZAURA C. N.. Modification of Gold's Work Function upon Adsorption of Mercaptobiphenylcarbonitrile: Experimental Evidence for a Theoretical Prediction. Journal of Physical Chemistry C, v. 122, n. 11, p. 6083-6092, . (12/13119-3)
FAZIO, ALEJANDRA T.; LOPEZ, MONICA MAMIAN; TEMPERINI, MARCIA L. A.; DE FARIA, DALVA LUCIA A.. Surface enhanced Raman spectroscopy and cultural heritage biodeterioration: Fungi identification in earthen architecture from Paraiba Valley (Sao Paulo, Brazil). VIBRATIONAL SPECTROSCOPY, v. 97, p. 129-134, . (12/13119-3, 14/07841-3, 12/05356-5)
SOUZA, KLESTER S.; DOS SANTOS, DIEGO P.; ANDRADE, GUSTAVO F. S.; PEREIRA, MARCELO B.; TEIXEIRA-NETO, ERICO; TEMPERINI, MARCIA L. A.. Molecular Wires Bridging Gaps between Gold Surfaces and Their Influence on SERS Intensities. Journal of Physical Chemistry C, v. 121, n. 38, p. 20937-20946, . (12/13119-3, 11/17923-9)
FARIA, LUIZ F. O.; LIMA, THAMIRES A.; FERREIRA, FABIO F.; RIBEIRO, MAURO C. C.. Ultraslow Phase Transitions in an Anion-Anion Hydrogen-Bonded Ionic Liquid. Journal of Physical Chemistry B, v. 122, n. 6, p. 1972-1980, . (15/05803-0, 12/13119-3, 14/15049-8)
FARIA, LUIZ F. O.; LIMA, THAMIRES A.; RIBEIRO, MAURO C. C.. Phase Transitions of the Ionic Liquid [C(2)C(1)im][NTf2] under High Pressure: A Synchrotron X-ray Diffraction and Raman Microscopy Study. Crystal Growth & Design, v. 17, n. 10, p. 5384-5392, . (15/05803-0, 12/13119-3, 14/15049-8)
PASCHOAL, VITOR H.; FARIA, LUIZ F. O.; RIBEIRO, MAURO C. C.. Vibrational Spectroscopy of Ionic Liquids. CHEMICAL REVIEWS, v. 117, n. 10, SI, p. 7053-7112, . (15/05803-0, 15/07516-8, 12/13119-3)
MONEZI, NATALIA M.; BORIN, ANTONIO C.; SANTOS, PAULO S.; ANDO, ROMULO A.. The thermochromic behavior of aromatic amine-SO2 charge transfer complexes. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, v. 173, p. 462-467, . (12/13119-3)
DA SILVA, ANDERSON G. M.; DE SOUZA, MICHELE L.; RODRIGUES, THENNER S.; ALVES, RAFAEL S.; TEMPERINI, MARCIA L. A.; CAMARGO, PEDRO H. C.. Rapid Synthesis of Hollow Ag-Au Nanodendrites in 15 Seconds by Combining Galvanic Replacement and Precursor Reduction Reactions. CHEMISTRY-A EUROPEAN JOURNAL, v. 20, n. 46, p. 15040-15046, . (12/13119-3, 13/10831-7, 13/19861-6)
FANETTI, SAMUELE; NOBREGA, MARCELO M.; TEIXEIRA-NETO, ERICO; TEMPERINI, MARCIA L. A.; BINI, ROBERTO. Effect of Structural Anisotropy in High-Pressure Reaction of Aniline. Journal of Physical Chemistry C, v. 122, n. 51, p. 29158-29164, . (12/13119-3, 14/15107-8, 15/09763-2)
VELDHORST, ARNO A.; FARIA, LUIZ F. O.; RIBEIRO, MAURO C. C.. Local solvent properties of imidazolium-based ionic liquids. JOURNAL OF MOLECULAR LIQUIDS, v. 223, p. 283-288, . (12/13119-3, 15/05803-0, 14/13134-8)
DE FARIA, DALVA L. A.; EDWARDS, HOWELL G. M.; CAREAGA, VALERIA; WALT, NICHOLAS; MAIER, MARTA S.. A definitive analytical spectroscopic study of Indian yellow, an ancient pigment used for dating purposes. Forensic Science International, v. 271, p. 1-7, . (12/13119-3, 11/13760-8)
MONEZI, NATALIA M.; ANDO, ROMULO A.. Resonance Raman and UV-VIS spectroscopic investigation of the reaction of tetracyanoethylene and N-methyldiphenylamine. Journal of Raman Spectroscopy, v. 48, n. 5, p. 758-764, . (12/13119-3)
DALVA L. A. DE FARIA; THIAGO S. PUGLIERI. DIFERENCIANDO REPRODUÇÕES E PINTURAS VERDADEIRAS: UM INTERESSANTE ESTUDO DE CASO. Química Nova, v. 39, n. 5, p. 542-547, . (11/13760-8, 12/13119-3)
TOMASINI, EUGENIA; CASTELLANOS RODRIGUEZ, DIANA; GOMEZ, BLANCA A.; DE FARIA, DALVA L. A.; RUA LANDA, CARLOS; SIRACUSANO, GABRIELA; MAIER, MARTA S.. A multi-analytical investigation of the materials and painting technique of a wall painting from the church of Copacabana de Andamarca (Bolivia). Microchemical Journal, v. 128, p. 172-180, . (12/13119-3, 11/13760-8)
BAR, JACIARA; MONEZI, NATALIA M.; ANDO, ROMULO A.. The solvation inhomogeneity of sulfur dioxide in 1-butyl-3-methylimidazolium thiocyanate ionic liquid probed by Raman spectroscopy. Journal of Raman Spectroscopy, v. 49, n. 2, p. 230-237, . (12/13119-3)
BEMARDINO, N. D.; CONSTANTINO, V. R. L.; DE FARIA, D. L. A.. Probing the Indigo Molecule in Maya Blue Simulants with Resonance Raman Spectroscopy. Journal of Physical Chemistry C, v. 122, n. 21, p. 11505-11515, . (11/50318-1, 12/05643-4, 12/13119-3)
VELDHORST, ARNO A.; RIBEIRO, MAURO C. C.. Mechanical heterogeneity in ionic liquids. Journal of Chemical Physics, v. 148, n. 19, . (12/13119-3, 14/13134-8)
BERNARDINO, NATHALIA D.; CONSTANTINO, VERA R. L.; DE FARIA, DALVA L. A.. Probing the chemical reactivity of interfaces: Investigation on the interaction of dehydroindigo with Laponite by UV-vis, Raman and infrared spectroscopy. VIBRATIONAL SPECTROSCOPY, v. 94, p. 83-88, . (12/13119-3, 11/50318-1, 12/05643-4)
PRYSTAJ COLOMBO, RAFAEL NERI; MOREIRA, RODRIGO VALIM; ARAUJO DE FARIA, DALVA LUCIA; CORDOBA DE TORRESI, SUSANA INES. Controlling Gold Electrodeposition on Porous Polymeric Templates Produced by the Breath-Figure Method: Fabrication of SERS-Active Surfaces. CHEMPLUSCHEM, v. 84, n. 8, p. 1052-1059, . (15/26308-7, 15/12786-4, 12/13119-3)
SILVA, CLAUDIO H. B.; ILIUT, MARIA; MURYN, CHRISTOPHER; BERGER, CHRISTIAN; COLDRICK, ZACHARY; CONSTANTINO, VERA R. L.; TEMPERINI, MARCIA L. A.; VIJAYARAGHAVAN, ARAVIND. Ternary nanocomposites of reduced graphene oxide, polyaniline and hexaniobate: hierarchical architecture and high polaron formation. BEILSTEIN JOURNAL OF NANOTECHNOLOGY, v. 9, p. 2936-2945, . (11/50318-1, 13/03013-6, 12/13119-3, 14/05048-4)
MONEZI, NATALIA M.; ANDO, ROMULO A.. Resonance Raman and UV-vis characterization of charge transfer complexes of TCNQ and aromatic amines. VIBRATIONAL SPECTROSCOPY, v. 99, p. 67-72, . (12/13119-3)

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