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Development of rare earth based light converters: luminescent markers, optical sensors, and amplifiers

Grant number: 21/08111-2
Support Opportunities:Research Projects - Thematic Grants
Duration: October 01, 2022 - September 30, 2027
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
Principal Investigator:Hermi Felinto de Brito
Grantee:Hermi Felinto de Brito
Host Institution: Instituto de Química (IQ). Universidade de São Paulo (USP). São Paulo , SP, Brazil
Pesquisadores principais:
( Atuais )		Fernando Aparecido Sigoli ; José Maurício Almeida Caiut ; Maria Claudia França da Cunha Felinto ; Rogéria Rocha Gonçalves ; Sidney José Lima Ribeiro
Pesquisadores principais:
( Anteriores )		Andrea Simone Stucchi de Camargo Alvarez Bernardez
Associated researchers:Andrea Simone Stucchi de Camargo Alvarez Bernardez ; Antonio Claudio Tedesco ; Danilo Manzani ; Danilo Mustafa ; Douglas Galante ; Duclerc Fernandes Parra ; Ercules Epaminondas de Sousa Teotonio ; Everton Bonturim ; Felipe da Silva Manrique Canisares ; Gianluca Camillo Azzellini ; Henrique Andrade Rodrigues da Fonseca ; Hiro Goto ; Israel Ferreira da Costa ; Israel Pereira de Assunção ; Itamar Tomio Neckel ; Ivan Guide Nunes da Silva ; José Maurício Almeida Caiut ; Jose Miranda de Carvalho Junior ; Karmel de Oliveira Lima ; Leonnam Gotardo Merizio ; Lucas Carvalho Veloso Rodrigues ; Luidgi Giordano ; Magnus Ake Gidlund ; Marcelo Cecconi Portes ; Paolo Di Mascio ; Paulo Cesar de Sousa Filho ; Paulo Roberto da Silva Santos ; Renaldo Tenório de Moura Júnior ; Renato Sanches Freire ; Verônica de Carvalho Teixeira ; Wagner de Mendonça Faustino ; Zahid Ullah Khan
Associated grant(s):24/02129-5 - Structural investigation of lanthanide compounds using the Electronic Paramagnetic Resonance (EPR) technique as a function of the ligand field, AP.R
24/01900-0 - Development of core-shell-shell nanoparticles based on UCNP, ZnO and ZIF-8 coupled to a bacterial cellulose membrane to combat microbial resistance through photoactivation, AP.R
23/06605-3 - 20th International Conference on Luminescence, AR.EXT
23/07503-0 - 20th International Conference on Luminescence, AR.EXT
Associated scholarship(s):24/05947-0 - "Development of 2D Materials based on Sulfide and Tin Oxide Doped with Rare Earth Ions for Application in Heterogeneous Photocatalysis assisted by visible light", BP.MS
24/09532-0 - Development of luminescent inks based on cellulose nanocrystals aimed at 3D printing of prototypes for photonic applications, BP.IC
23/16684-8 - Multifunctional platforms based on inorganic-organic hybrids UCNPS@SiO2-Ln3+-Ir3+ aiming for sensing, cell imaging, and singlet oxygen generation by upconversion process, BP.PD
 + associated scholarships 24/01502-4 - Synthesis and photoluminescent study of lead-free A2BIBIIIX6-type double perovskite embedded in boron-germanate glasses, BP.MS
24/00198-0 - Hierarchical luminescent core@shell nanocrystals based on rare earth fluorides for intracellular temperature sensing and imaging, BP.PD
24/04100-4 - Development of Upconversion Nanoparticle@MOF core-shell theranostic systems for cancer treatment, BP.TT
23/07987-7 - Development of an optical platform based on photoluminescent films on glass and commercial optical fibers for potential application in gas sensing of biomedical interest, BP.DR
24/01581-1 - Niobate and tantalate perovskites doped with lanthanide ions and transition metals for applications in photonics and photocatalysis, BP.DD
23/12648-7 - Development of lanthanide containing vitreous MOF systems, BP.IC
23/07220-8 - Development of Layered Double Hydroxide/Copper-Cysteamine Nanoparticles Systems for Environmental Applications: Pharmaceuticals Degradation, Pathogens Inactivation and Sensing, BP.PD
23/08783-6 - Development of glass and glass-ceramic substrates based on bismuth and vanadium phosphates for photocatalytic applications, BP.IC
23/05351-8 - Development of lanthanide-doped persistent luminescence perovskite oxide nanoparticles for bioimaging and security labeling, BP.PD
23/13147-1 - Bright Europium and terbium ²-diketonate complexes with phenanthro-imidazole ligands for biomarker applications, BP.IC
23/09213-9 - "Development of Red persistent luminescent Rare earth niobate doped with Pr3+", BP.IC
23/08128-8 - Rare-earth doping effect in cerium oxysulfide, BP.IC
22/16692-8 - "Rare earth ion-doped tantalate nanoparticles with persistent luminescence, energy upconversion and near-infrared emission for applications in nanomedicine", BP.DR
23/02179-0 - Rare-earth doped fluorophosphate glass and glass-ceramics for luminescent thermometry application, BP.IC
23/02852-6 - "Lanthanide doped Alkali/alkaline earth niobates and germanates: Studies of Persistent Luminescence to Active planar waveguide"., BP.DR
22/14602-1 - DEVELOPMENT OF BIOCELLULOSE-FIBROIN CONDUCTIVE SUBSTRATES FOR RETINAL IMPLANTS APPLICATIONS, BP.IC
19/23763-6 - Triplet state direct excitation on trivalent lanthanide complexes, BP.PD - associated scholarships

Abstract

This proposal aims to develop new micro and nanostructured luminescent materials based on ra-earth ions (TR:Sc, Y, La-Lu) with applications in the energy area, health, telecommunication, radiation detection, and safety. Different strategies will be undertaken to develop new luminescent materials focused on the energy converter area, such as i) Molecular light-converting devices through the ligand-metal intramolecular energy transfer for application in molecular thermometers and optical markers; ii) Biomarkers and multifunctional materials for bioimaging, detection, and photoactivation in photodynamic therapy; iii) Light energy converters that act as high-efficiency light emitters for LED applications; iv) Photocatalytic composites that have high efficiency of chemical conversion, v) Optical amplifiers for application in telecommunications and vi) Scintillators for high-energy radiation detection. The material's photophysical properties will be directly correlated with their morphological and structural characteristics, representing the basic science approach of the proposal. Another goal of this research project is to train highly qualified human resources to develop new light-converting devices. Therefore, the research project also aims to contribute to position the country in a prominent place in light-converting materials concerning scientific and technological advances to improve modern society's quality of life. (AU)

Articles published in Agência FAPESP Newsletter about the research grant:
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Articles published in other media outlets ( ):
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VEICULO: TITULO (DATA)
VEICULO: TITULO (DATA)

Publicações científicas (10)
(Referências obtidas automaticamente do Web of Science e do SciELO, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores)
MANFRE, MATEUS GRECCO; LABAKI, HAYRA DO PRADO; DE SOUZA, VITOR DOS SANTOS; GONCALVES, ROGERIA R.. Red and near-infrared emitting phosphors based on Eu3+- or Nd3+-doped lanthanum niobates prepared by the sol-gel route. DALTON TRANSACTIONS, v. 51, n. 46, p. 14-pg., . (21/08111-2, 20/05319-9)
LIMA, DEBORAH A.; BISPO JR, AIRTON G.; GALICO, DIOGO A. .; COELHO, SERGIO F. N.; NETO, JOAO H. ARAUJO; ELLENA, JAVIER A.; PETIOTE, LANOUSSE; MAZALI, ITALO O.; SIGOLI, FERNANDO A. .. Tuning the Thermometric Features in 1D Luminescent EuIII and TbIII Coordination Polymers through Different Bridge Phosphine Oxide Ligands. Inorganic Chemistry, v. 62, n. 17, p. 9-pg., . (21/04876-4, 20/02614-0, 21/08111-2, 17/08098-0, 21/06326-1)
BISPO-JR, AIRTON GERMANO; YEH, LAURENCE; ERRULAT, DYLAN; GALICO, DIOGO ALVES; SIGOLI, FERNANDO APARECIDO; MURUGESU, MURALEE. Improving the performance of & beta;-diketonate-based Dy-III single-molecule magnets displaying luminescence thermometry. CHEMICAL COMMUNICATIONS, v. 59, n. 56, p. 4-pg., . (19/23763-6, 21/09755-0, 21/06326-1, 21/08111-2)
PESSOA, ALLISON R.; GALINDO, JEFFERSON A. O.; DOS SANTOS, LUIZ F.; GONCALVES, ROGERIA R.; MAIER, STEFAN A.; MENEZES, LEONARDO DE S.; AMARAL, ANDERSON M.. Correction Due to Nonthermally Coupled Emission Bands and Its Implications on the Performance of Y2O3:Yb3+ /Er3+ Single-Particle Thermometers. Journal of Physical Chemistry C, v. 127, n. 20, p. 8-pg., . (17/11301-2, 20/04157-5, 20/05319-9, 21/08111-2)
KHAN, ZAHID U.; KHAN, LATIF U.; UCHIYAMA, MAYARA K.; PRADO, FERNANDA M.; FARIA, RODRIGO L.; COSTA, ISRAEL F.; MIYAMOTO, SAYURI; ARAKI, KOITI; GIDLUND, MAGNUS; BRITO, HERMI F.; et al. Singlet Molecular Oxygen Generation via Unexpected Emission Color-Tunable CdSe/ZnS Nanocrystals for Applications in Photodynamic Therapy. ACS APPLIED NANO MATERIALS, v. N/A, p. 14-pg., . (18/21489-1, 21/00356-6, 21/08111-2, 12/12663-1, 13/07937-8)
DE MORAIS, AMANDA JUSTINO; BISPO-JR, AIRTON GERMANO; FERREIRA, FLAVIA DE SOUSA; MAZALI, ITALO ODONE; SIGOLI, FERNANDO APARECIDO. Multi-emission processes of hierarchically structured NaGdF4:Tm:Yb:Tb core@shell nanoparticles. NEW JOURNAL OF CHEMISTRY, v. 47, n. 15, p. 8-pg., . (20/02614-0, 21/08111-2, 21/06326-1)
CAPELO, RENATO GRIGOLON; BALTIERI, RICARDO SANTOS; DE OLIVEIRA JR, MARCOS; MANZANI, DANILO. Exploring the Influence of ZnF2 on Zinc-Tellurite Glass: Unveiling Changes in OH Content, Structure, and Optical Properties. ACS OMEGA, v. 8, n. 38, p. 9-pg., . (20/12280-1, 21/08111-2, 20/11038-2)
PAOLINI, TIAGO B.; ASSUNCAO, ISRAEL P.; COSTA, ISRAEL F.; BLOIS, LUCCA; FELINTO, MARIA CLAUDIA F. C.; MOURA JR, RENALDO T.; TEOTONIO, ERCULES E. S.; MALTA, OSCAR L.; NETO, ALBANO N. CARNEIRO; BRITO, HERMI F.. The influence of imidazolium counterions on the luminescence properties of Cnmim[Eu(tta)4] tetrakis complexes in solid-state and ionic liquid solutions. Journal of Luminescence, v. 263, p. 11-pg., . (21/08111-2, 22/12709-3)
PASSINI, LUAN N.; MATURI, FERNANDO E.; PUGINA, ROBERTA S.; HILARIO, ELOISA G.; FONTES, MARINA; BARUD, HERNANE S.; CARLOS, LUIS D.; CAIUT, JOSE MAURICIO A.; MANZANI, DANILO. Luminescent Pb-free perovskites: low-cytotoxicity materials for primary thermal sensing. JOURNAL OF MATERIALS CHEMISTRY C, v. 11, n. 23, p. 10-pg., . (21/08111-2, 19/18828-1, 18/16126-7)
BISPO-JR, AIRTON G.; GALICO, DIOGO A.; DIAZ-RODRIGUEZ, ROBERTO M.; OVENS, JEFFREY S.; SIGOLI, FERNANDO A.; MURUGESU, MURALEE. The role of terminal ligands in the slow relaxation of magnetisation and luminescence thermometry of dinuclear Nd-III complexes. INORGANIC CHEMISTRY FRONTIERS, v. 10, n. 13, p. 11-pg., . (21/08111-2, 12/11382-9, 21/06326-1, 19/23763-6, 21/09755-0)

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