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Photo (electro) catalysis and photoelectro-fenton processes for emerging contaminants removal from industrial wastewater

Abstract

The international network PHOCATPROS Brazil-Chile (BR-CL) is focused in the synthesis and characterization of new semiconductors materials based on Nb/Nb2O5 nanotubes modified with Fe2O3, Nb/Nb2O5 doped with B, TiO2 nanotubes modified with Ag nanoparticles and FTO/Fe2O3 by electrochemical deposition; and molecular organic framework (MOF) structures through anodic deposition on metallic electrodes Cu, Ni, Zn and Fe containing the binder (2-aminoterephthalic acid (ATP) and bipyridine (ATP-NH2), aminobenzene-1,4-dicarboxylic acid (BDC)) for the formation of the three-dimensional metal-organic network. The MOF thin films electrodes will be prepared by anodic deposition on zinc, nickel, copper and iron metal electrodes in the presence of the ligand with the aim to obtain materials with different characteristics to be applied in photocatalysis/photoelectrocatalysis of emerging contaminants in water. Moreover, the heterogeneous solar photoelectro-Fenton process, using the new photocatalysts/photoelectrocatalysts (PC/PEC), will be applied to treat wastewater containing specific emerging contaminants (EC) in synthetic wastewater and real industrial wastewater using different solar photoelectrochemical reactors to be evaluated for potential industrial-scale application . For this reason, a complete analytical characterization of different industrial wastewater (textile industry, winery industry and meat industry) will be performed. After, a chemical evaluation of the heterogeneous SPEF process: concentration of reagents (new catalyst concentration, supporting electrolytes, between others), intermediates and products formed during the different decontamination methods of the EC, kinetics evaluation of the degradation of each EC studied, quantification of electrogenerated oxidants, etc. Moreover, a complete evaluation of energetic costs for each process is proposed too, evaluating the possibility of its potential industrial application. During the develop of the scientific proposal, our collaborative project PHOCATPROSS includes missions in Brazil and Chile, conferences, dissemination of research in media outside the academy, increases the quantity and quality of the research and strengthen collaborative research between Chile and Brazil. (AU)

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Scientific publications (40)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
MEDEIROS DE ARAUJO, DANYELLE; DOS SANTOS, ELISAMA V.; MARTINEZ-HUITLE, CARLOS A.; DE BATTISTI, ACHILLE. Achieving Electrochemical-Sustainable-Based Solutions for Monitoring and Treating Hydroxychloroquine in Real Water Matrix. APPLIED SCIENCES-BASEL, v. 12, n. 2, . (19/13113-4, 14/50945-4)
SILVA, IASMIN B.; DE ARAUJO, DANYELLE MEDEIROS; VOCCIANTE, MARCO; FERRO, SERGIO; MARTINEZ-HUITLE, CARLOS A.; DOS SANTOS, ELISAMA V.. Electrochemical Determination of Lead Using A Composite Sensor Obtained from Low-Cost Green Materials:Graphite/Cork. APPLIED SCIENCES-BASEL, v. 11, n. 5, . (14/50945-4, 19/13113-4)
CANDIA-ONFRAY, CHRISTIAN; ROJAS, SUSANA; BOLDRIN ZANONI, MARIA VALNICE; SALAZAR, RICARDO. n updated review of metal-organic framework materials in photo(electro)catalytic applications: From CO2 reduction to wastewater treatment. CURRENT OPINION IN ELECTROCHEMISTRY, v. 26, . (19/13113-4)
GANIYU, SOLIU O.; DOS SANTOS, ELISAMA VIEIRA A.; MARTINEZ-HUITLE, CARLOS R.; WALDVOGEL, SIEGFRIED. Opportunities and challenges of thin-film boron-doped diamond electrochemistry for valuable resources recovery from waste: Organic, inorganic, and volatile product electrosynthesis. CURRENT OPINION IN ELECTROCHEMISTRY, v. 32, p. 12-pg., . (14/50945-4, 19/13113-4)
MARTINEZ-HUITLE, CARLOS A.; EINAGA, YASUAKI; OTURAN, MEHMET A.. Conductive-synthetic diamond materials in meeting the sustainable development goals. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, v. 26, n. 5, p. 3-pg., . (19/13113-4, 14/50945-4)
BARBOSA FERREIRA, MAIARA; SALES SOLANO, ALINE MARIA; VIEIRA DOS SANTOS, ELISAMA; MARTINEZ-HUITLE, CARLOS A.; GANIYU, SOLIU O.. Coupling of Anodic Oxidation and Soil Remediation Processes: A Review. MATERIALS, v. 13, n. 19, . (14/50945-4, 19/13113-4)
BRITO, LAYSA R. D.; GANIYU, SOLIU O.; DOS SANTOS, ELISAMA V.; OTURAN, MEHMET A.; MARTINEZ-HUITLE, CARLOS A.. Removal of antibiotic rifampicin from aqueous media by advanced electrochemical oxidation: Role of electrode materials, electrolytes and real water matrices. Electrochimica Acta, v. 396, . (19/13113-4, 14/50945-4)
SANTOS, JOSE EUDES L.; DA SILVA, DJALMA R.; MARTINEZ-HUITLE, CARLOS A.; DOS SANTOS, ELISAMA VIEIRA; QUIROZ, MARCO A.. Cathodic hydrogen production by simultaneous oxidation of methyl red and 2,4-dichlorophenoxyacetate in aqueous solutions using PbO2, Sb-doped SnO2 and Si/BDD anodes. Part 2: hydrogen production. RSC ADVANCES, v. 10, n. 62, p. 37947-37955, . (19/13113-4, 14/50945-4)
HENRIQUE, JOAO MILLER DE MELO; CANIZARES, PABLO; SAEZ, CRISTINA; DOS SANTOS, ELISAMA VIEIRA; RODRIGO, MANUEL ANDRES. Relevance of gaseous flows in electrochemically assisted soil thermal sremediation. CURRENT OPINION IN ELECTROCHEMISTRY, v. 27, . (14/50945-4, 19/13113-4)
VIEIRA, GLEILSON DE F.; SEGUNDO, INALMAR D. BARBOSA; SANTOS, JOSE EUDES L.; GONDIM, AMANDA D.; DOS SANTOS, ELISAMA V.; MARTINEZ-HUITLE, CARLOS A.. hr Electro-oxidation of wastewater from a beauty salon: The influence of electrolyte type in the removal of organic load and energy consumption. PROCESS SAFETY AND ENVIRONMENTAL PROTECTION, v. 177, p. 12-pg., . (14/50945-4, 19/13113-4)
SEGUNDO, INALMAR D. BARBOSA; CARDOZO, JUSSARA C.; CASTRO, POLLYANA SOUZA; GONDIM, AMANDA D.; DOS SANTOS, ELISAMA V.; MARTINEZ-HUITLE, CARLOS A.. Cost-effective smartphone-based method for low range chemical oxygen demand analysis *. METHODSX, v. 11, p. 6-pg., . (14/50945-4, 19/13113-4)
PRATES, MATHEUS PIMENTEL; MARCIONILIO, SUZANA MARIA DE OLIVEIRA LOURES; MACHADO, KARINE BORGES; DE ARAUJO, DANYELLE MEDEIROS; MARTINEZ-HUITLE, CARLOS A.; ARANTES, ARIZEU LUIZ LEAO; GADELHA, JOSE EDUARDO FERREIRA DA SILVA. Fenton: A Systematic Review of Its Application in Wastewater Treatment. PROCESSES, v. 11, n. 8, p. 26-pg., . (14/50945-4, 19/13113-4)
OLIVEIRA, HERBET L.; BARROS, THALITA M.; SANTOS, JOSE E. L.; GONDIM, AMANDA D.; QUIROZ, MARCO A.; MARTINEZ-HUITLE, CARLOS A.; DOS SANTOS, ELISAMA V.. Electrochemical oxidation of a real effluent using selective cathodic and anodic strategies to simultaneously produce high value-added compounds: Green hydrogen and carboxylic acids. Electrochemistry Communications, v. 154, p. 7-pg., . (14/50945-4, 19/13113-4)
DOS SANTOS, ELISAMA VIEIRA; MARTINEZ-HUITLE, CARLOS A.; RODRIGO, MANUEL A.. The electro-refinery in organics: A new arising concept for valorization of wastes. CURRENT OPINION IN ELECTROCHEMISTRY, v. 39, p. 17-pg., . (14/50945-4, 19/13113-4)
GANIYU, SOLIU O.; GOMES DE ARAUJO, MARIA JOSE; DE ARAUJO COSTA, EMILY C. T.; LIMA SANTOS, JOSE EUDES; DOS SANTOS, ELISAMA VIEIRA; MARTINEZ-HUITLE, CARLOS A.; CASTELLA PERGHER, SIBELE BERENICE. Design of highly efficient porous carbon foam cathode for electro-Fenton degradation of antimicrobial sulfanilamide. APPLIED CATALYSIS B-ENVIRONMENTAL, v. 283, . (19/13113-4, 14/50945-4)
SILVA, KARYN N. O.; HENRIQUE, JOAO M. M.; VILAR, VITOR J. P.; MARTINEZ-HUITLE, CARLOS A.; DOS SANTOS, ELISAMA, V. Cork-based permeable reactive barriers coupled to electrokinetic processes for interrupting pollutants reaching groundwater: a case study of lead-contaminated soil. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, v. 97, n. 10, p. 10-pg., . (19/13113-4, 14/50945-4)
CERRO-LOPEZ, MONICA; CASTRO-PASTRANA, LUCILA I.; CAMPOS-DELGADO, JESSICA; RUBIO-ROSAS, EFRAIN; BUSTOS, ERIKA; MARTINEZ-HUITLE, CARLOS A.. Mesostructured lead dioxide grown on titania nanotubes for diclofenac water removal through electrocatalytic and photoelectrocatalytic processes. Environmental Research, v. 231, p. 12-pg., . (14/50945-4, 19/13113-4)
CANDIA-ONFRAY, CHRISTIAN; IRIKURA, KALLYNI; CALZADILLA, WENDY; ROJAS, SUSANA; ZANONI, MARIA VALNICE BOLDRIN; SALAZAR, RICARDO. Degradation of contaminants of emerging concern in a secondary effluent using synthesized MOF-derived photoanodes: A comparative study between photo-, electro- and photoelectrocatalysis. Chemosphere, v. 315, p. 11-pg., . (14/50945-4, 19/13113-4, 17/12790-7)
ESCALONA-DURAN, FLORYMAR; SAEZ, CRISTINA; LOBATO, JUSTO; MARTINEZ-HUITLE, CARLOS A.; RODRIGO, MANUEL ANDRES. Electroscrubbers for removing volatile organic compounds and odorous substances from polluted gaseous streams. CURRENT OPINION IN ELECTROCHEMISTRY, v. 28, . (14/50945-4, 19/13113-4)
SILVA, AMISON RICK L.; MARTINEZ-HUITLE, CARLOS A.. Theoretical studies of dimers and properties of the corrosion inhibitor profile for semicarbazones and thiosemicarbazones. JOURNAL OF MOLECULAR LIQUIDS, v. 343, . (19/13113-4, 14/50945-4)
DA COSTA SOARES, IZABELLE CRISTINA; LOPES DA SILVA, AMISON RICK; MARTINS DE MOURA SANTOS, ELAINE CRISTINA; DOS SANTOS, ELISAMA VIEIRA; DA SILVA, DJALMA RIBEIRO; MARTINEZ-HUITLE, CARLOS A.. Understanding the electrochemical oxidation of dyes on platinum and boron-doped diamond electrode surfaces: experimental and computational study. Journal of Solid State Electrochemistry, . (14/50945-4, 19/13113-4)
DA COSTA SOARES, IZABELLE CRISTINA; LOPES DA SILVA, AMISON RICK; MARTINS DE MOURA SANTOS, ELAINE CRISTINA; DOS SANTOS, ELISAMA VIEIRA; DA SILVA, DJALMA RIBEIRO; MARTINEZ-HUITLE, CARLOS A.. Understanding the electrochemical oxidation of dyes on platinum and boron-doped diamond electrode surfaces: experimental and computational study. Journal of Solid State Electrochemistry, v. 24, n. 11-12, SI, p. 3245-3256, . (14/50945-4, 19/13113-4)
DE ARAUJO, DANYELLE M.; PAIVA, SUELYA DA SILVA M.; HENRIQUE, JOAO MILLER M.; MARTINEZ-HUITLE, CARLOS A.; DOS SANTOS, V, ELISAMA. Green Composite Sensor for Monitoring Hydroxychloroquine in Different Water Matrix. MATERIALS, v. 14, n. 17, . (19/13113-4, 14/50945-4)
MONTEIRO, MAYRA KEROLLY SALES; MONTEIRO, MAYARA MARIA SALES; HENRIQUE, ANDRE MILLER DE MELO; LLANOS, JAVIER; SAEZ, CRISTINA; DOS SANTOS, ELISAMA VIEIRA; RODRIGO, MANUEL ANDRES. A review on the electrochemical production of chlorine dioxide from chlorates and hydrogen peroxide. CURRENT OPINION IN ELECTROCHEMISTRY, v. 27, . (14/50945-4, 19/13113-4)
ANDRADE, DEBORAH C.; DOLIC, MAJA B.; MARTINEZ-HUITLE, CARLOS A.; DOS SANTOS, ELISAMA, V; SILVA, TANIA F. C., V; VILAR, VITOR J. P.. Coupling electrokinetic with a cork-based permeable reactive barrier to prevent groundwater pollution: A case study on hexavalent chromium-contaminated soil. Electrochimica Acta, v. 429, p. 17-pg., . (19/13113-4, 14/50945-4)
DE SOUZA, JOAO CARLOS; IRIKURA, KALLYNI; MANTILLA, HERNAN DARIO ROJAS; ZANONI, MARIA VALNICE BOLDRIN; SALAZAR, RICARDO. Using 3D printed magnetic platform as support for screen printed electrode applied for p-toluenediamine detection in biological fluid and water samples. Analytica Chimica Acta, v. 1240, p. 13-pg., . (19/13113-4, 15/12998-1, 14/50945-4)
CRISPIM, ALANA C.; DE ARAUJO, DANYELLE M.; MARTINEZ-HUITLE, CARLOS A.; SOUZA, FERNANDA L.; DOS SANTOS, ELISAMA, V. Application of electro-Fenton and photoelectro-Fenton processes for the degradation of contaminants in landfill leachate. Environmental Research, v. 213, p. 11-pg., . (19/13113-4, 14/50945-4)
CARDOZO, JUSSARA CAMARA; DA SILVA, DJALMA RIBEIRO; MARTINEZ-HUITLE, CARLOS A.; QUIROZ, MARCO ANTONIO; DOS SANTOS, ELISAMA VIEIRA. The versatile behavior of diamond electrodes - Electrochemical examination of the anti-psychotic drug olanzapine (OL) oxidation as a model organic aqueous solution. Electrochimica Acta, v. 411, p. 10-pg., . (19/13113-4, 14/50945-4)
CRISPIM, ALANA CAROLYNE; MENDONCA DE PAIVA, SUELYA DA SILVA; DE ARAUJO, DANYELLE MEDEIROS; SOUZA, FERNANDA LOURDES; DOS SANTOS, ELISAMA VIEIRA. Ultrasound and UV technologies for wastewater treatment using boron-doped diamond anodes. CURRENT OPINION IN ELECTROCHEMISTRY, v. 33, p. 11-pg., . (19/13113-4, 14/50945-4)
ARAUJO, KARLA C. F.; DOS SANTOS, ELISAMA, V; NIDHEESH, PUTHIYA, V; MARTINEZ-HUITLE, CARLOS A.. Fundamentals and advances on the mechanisms of electrochemical generation of persulfate and sulfate radicals in medium. CURRENT OPINION IN CHEMICAL ENGINEERING, v. 38, p. 12-pg., . (19/13113-4, 14/50945-4)
SILVA, KARYN N. O.; HENRIQUE, JOAO M. M.; DOLIC, MAJA B.; MARTINEZ-HUITLE, CARLOS A.; DOS SANTOS, ELISAMA, V; MOREIRA, FRANCISCA C.; VILAR, VITOR J. P.. Integration of soil washing and cork permeable reactive barriers for the remediation of soil contaminated with polycyclic aromatic hydrocarbons. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, v. 97, n. 12, p. 11-pg., . (19/13113-4)
VILAR, VITOR J. P.; DOS SANTOS, ELISAMA V.; MARTINEZ-HUITLE, CARLOS A.. Advanced oxidation/reduction technologies: a perspective from Iberoamerican countries. Environmental Science and Pollution Research, v. 28, n. 19, p. 3-pg., . (19/13113-4, 14/50945-4)
BARROS, THALITA MEDEIROS; DE ARAUJO, DANYELLE MEDEIROS; LEMOS DE MELO, ALANA TAMIRES; MARTINEZ-HUITLE, CARLOS ALBERTO; VOCCIANTE, MARCO; FERRO, SERGIO; DOS SANTOS, ELISAMA VIEIRA. An Electroanalytical Solution for the Determination of Pb2+ in Progressive Hair Dyes Using the Cork-Graphite Sensor. SENSORS, v. 22, n. 4, p. 15-pg., . (19/13113-4, 14/50945-4)
DE FREITAS ARAUJO, KARLA CAROLINE; DOS SANTOS, ELISAMA VIEIRA; PIERPAOLI, MATTIA; FICEK, MATEUSZ; SANTOS, JOSE EUDES L.; MARTINEZ-HUITLE, CARLOS A.; BOGDANOWICZ, ROBERT. Diamondized carbon nanoarchitectures as electrocatalytic material for sulfate-based oxidizing species electrogeneration. Electrochimica Acta, v. 430, p. 11-pg., . (19/13113-4, 14/50945-4)
ARAUJO, KARLA CAROLINE DE FREITAS; COSTA, EMILY CINTIA TOSSI DE ARAUJO; DE ARAUJO, DANYELLE MEDEIROS; SANTOS, ELISAMA V.; MARTINEZ-HUITLE, CARLOS A.; CASTRO, POLLYANA SOUZA. Probing the Use of Homemade Carbon Fiber Microsensor for Quantifying Caffeine in Soft Beverages. MATERIALS, v. 16, n. 5, p. 14-pg., . (14/50945-4, 19/13113-4)
ARAUJO, KARLA C. F.; SILVA, KARYN N. O.; MONTEIRO, MAYRA K. S.; DA SILVA, DJALMA R.; QUIROZ, MARCO A.; DOS SANTOS, ELISAMA, V; MARTINEZ-HUITLE, CARLOS A.. Towards Use of Persulfate Electrogenerated at Boron Doped Diamond Electrodes as Ex-Situ Oxidation Approach: Storage and Service-Life Solution Parameters. Journal of the Electrochemical Society, v. 169, n. 3, p. 9-pg., . (19/13113-4, 14/50945-4)
OLIVEIRA DA SILVA, JULIO CESAR; SALES SOLANO, ALINE MARIA; BARBOSA SEGUNDO, INALMAR D.; DOS SANTOS, ELISAMA VIEIRA; MARTINEZ-HUITLE, CARLOS A.; DA SILVA, DJALMA RIBEIRO. Achieving Sustainable Development Goal 6 Electrochemical-Based Solution for Treating Groundwater Polluted by Fuel Station. WATER, v. 14, n. 18, p. 15-pg., . (19/13113-4, 14/50945-4)
ZHAO, GUOHUA; YANG, NIANJUN; MARTINEZ-HUITLE, CARLOS A.. Editorial overview: Diamond electrochemistry current advances, challenges and opportunities in diamond electrochemistry. CURRENT OPINION IN ELECTROCHEMISTRY, v. 36, p. 6-pg., . (19/13113-4, 14/50945-4)
CANDIA-ONFRAY, CHRISTIAN; ROJAS, SUSANA; BOLDRIN ZANONI, MARIA VALNICE; SALAZAR, RICARDO. An updated review of metal-organic framework materials in photo(electro)catalytic applications: From CO2 reduction to wastewater treatments. CURRENT OPINION IN ELECTROCHEMISTRY, v. 26, p. 7-pg., . (19/13113-4)
SANTOS, JOSE EUDES L.; DA SILVA, DJALMA R.; MARTINEZ-HUITLE, CARLOS A.; DOS SANTOS, ELISAMA VIEIRA; QUIROZ, MARCO A.. Cathodic hydrogen production by simultaneous oxidation of methyl red and 2,4-dichlorophenoxyacetate aqueous solutions using Pb/PbO2, Ti/Sb-doped SnO2 and Si/BDD anodes. Part 1: electrochemical oxidation. RSC ADVANCES, v. 10, n. 62, p. 37695-37706, . (14/50945-4, 19/13113-4)

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